中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Spectroscopic Characteristics of Longxi Nephrite From Sichuan and Its Color Genesis

文献类型:期刊论文

作者Fu Wan-lu1,2; Lu Hao3; Chai Jun4; Sun Zuo-yu1
刊名SPECTROSCOPY AND SPECTRAL ANALYSIS
出版日期2023-05-01
卷号43期号:5页码:1408-1412
ISSN号1000-0593
关键词Longxi nephrite Raman spectroscopy mu-XRF scanning Color genesis
DOI10.3964/j.issn.1000-0593(2023)05-1408-05
通讯作者Lu Hao(luchengze@bnu.edu.cn)
英文摘要Sichuan Longxi nephrite is important in ancient Shu (ancient Sichuan) jade culture. In order to get the basic mineral, chemical and spectroscopic characteristics of Sichuan Longxi nephrite with different colors, exploring its significant implications for identifying the jade color and alteration color of nephrite unearthed in Sichuan, lithologic thin section analysis, laser Raman spectroscopy, X-ray fluorescence spectroscopy and mu-XRF scanning were conducted on Longxi nephrite samples with different colors. The systematic field geological survey and sample collection shows that the color bands of Longxi nephrite outcrop have clear boundaries of grey black-green-white-green-gray black. The Longxi nephrite mainly comprises tremolite, containing a small amount of muscovite, calcite, apatite and other accessory minerals. The light bands contain calcite veins, and the dark bands contain relatively more accessory minerals. The Longxi nephrite samples in different colors have almost the same Raman spectra of tremolite with Raman peaks at 174, 228, 376, 392, 674, 935, 1 027, 1 061 cm(-1) and the single peak of hydroxyl at 3 675 cm i in the range of 3 600 similar to 3 700 cm(-1). None, characteristic Raman peaks of actinolite or graphite, indicate that the dark color of Longxi nephriteis not from dark-color minerals. The XRF analysis reveals that the main chemical compositions of Longxi nephrite samples are SiO2 (55. 20%0 similar to 57. 94%), MgO (24. 10%similar to 25. 00%), CaO (12. 60%0 similar to 13. 80%), Al2O3 (0. 39% similar to 1. 77%), and iron oxide (0. 25%similar to 0. 42%). FeO is the main iron oxide tested by the Fe-VOL05 titration method, and there is no significant correlation between the Fe2+ content and the colors of Longxi nephrite. The mu-XRF scanning results indicate that Si and Mg are relatively high in black-deep gray Longxi nephrite, and the contents of V and Cr are relatively high in green-white Longxi nephrite. The contents of common coloring elements in jade, such as Fe, Mn and Cu, do not vary in different color bands of Longxi nephrite. It further proves that V and Cr lead to the green color in Longxi nephrite. The analysis of spectral characteristics and coloring mechanism based on nondestructive identification can be fully applied to the comparative raw material study of ancient jade arte facts, providing scientific data for provenance research on jade material and jade culture of ancient Shu culture.
WOS研究方向Spectroscopy
语种英语
出版者OFFICE SPECTROSCOPY & SPECTRAL ANALYSIS
WOS记录号WOS:001027826000011
源URL[http://ir.nigpas.ac.cn/handle/332004/42563]  
专题中国科学院南京地质古生物研究所
通讯作者Lu Hao
作者单位1.Peking Univ, Sch Earth & Space Sci, Beijing 100871, Peoples R China
2.Chinese Acad Sci, State Key Lab Palaeobiol & Stratig, Nanjing Inst Geol & Palaeontol, Nanjing 210008, Peoples R China
3.Beijing Normal Univ, Sch Hist, Beijing 100875, Peoples R China
4.Peking Univ, Sch Archaeol & Museol, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Fu Wan-lu,Lu Hao,Chai Jun,et al. Spectroscopic Characteristics of Longxi Nephrite From Sichuan and Its Color Genesis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2023,43(5):1408-1412.
APA Fu Wan-lu,Lu Hao,Chai Jun,&Sun Zuo-yu.(2023).Spectroscopic Characteristics of Longxi Nephrite From Sichuan and Its Color Genesis.SPECTROSCOPY AND SPECTRAL ANALYSIS,43(5),1408-1412.
MLA Fu Wan-lu,et al."Spectroscopic Characteristics of Longxi Nephrite From Sichuan and Its Color Genesis".SPECTROSCOPY AND SPECTRAL ANALYSIS 43.5(2023):1408-1412.

入库方式: OAI收割

来源:南京地质古生物研究所

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