A non-phosgene route for synthesis of methyl N-phenyl carbamate derived from CO2 under mild conditions
文献类型：期刊论文
| 作者 | Gao, Junjie; Li, Huiquan; Zhang, Yifei; Zhang, Yi |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2007-06-01 |
| 卷号 | 9期号:6页码:572-576 |
| 关键词 | dimethyl carbonate synthesis ureas catalysts methanol carbonylation solvent amines |
| ISSN号 | 1463-9262 |
| 其他题名 | Green Chem. |
| 中文摘要 | A non-phosgene route for the synthesis of methyl N-phenyl carbamate from dimethyl carbonate and N,N'-diphenyl urea was studied under the mild conditions of atmospheric pressure. A series of homogenous and heterogenous catalysts were screened, and the homogenous catalyst sodium methoxide exhibited excellent activity in the synthesis of methyl N-phenyl carbamate under atmospheric pressure. The parameters of molar ratio of reactants, catalyst concentration, reaction time, number of additions of catalyst, reaction temperature and solvents in the synthesis of methyl N-phenyl carbamate were also investigated. A possible reaction mechanism with catalyst sodium methoxide was proposed. |
| 英文摘要 | A non-phosgene route for the synthesis of methyl N-phenyl carbamate from dimethyl carbonate and N,N'-diphenyl urea was studied under the mild conditions of atmospheric pressure. A series of homogenous and heterogenous catalysts were screened, and the homogenous catalyst sodium methoxide exhibited excellent activity in the synthesis of methyl N-phenyl carbamate under atmospheric pressure. The parameters of molar ratio of reactants, catalyst concentration, reaction time, number of additions of catalyst, reaction temperature and solvents in the synthesis of methyl N-phenyl carbamate were also investigated. A possible reaction mechanism with catalyst sodium methoxide was proposed. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | DIMETHYL CARBONATE SYNTHESIS ; UREAS ; CATALYSTS ; METHANOL ; CARBONYLATION ; SOLVENT ; AMINES |
| 收录类别 | ISTP ; SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000247782600009 |
| 公开日期 | 2013-10-15 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/3311]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Junjie,Li, Huiquan,Zhang, Yifei,et al. A non-phosgene route for synthesis of methyl N-phenyl carbamate derived from CO2 under mild conditions[J]. GREEN CHEMISTRY,2007,9(6):572-576. |
| APA | Gao, Junjie,Li, Huiquan,Zhang, Yifei,&Zhang, Yi.(2007).A non-phosgene route for synthesis of methyl N-phenyl carbamate derived from CO2 under mild conditions.GREEN CHEMISTRY,9(6),572-576. |
| MLA | Gao, Junjie,et al."A non-phosgene route for synthesis of methyl N-phenyl carbamate derived from CO2 under mild conditions".GREEN CHEMISTRY 9.6(2007):572-576. |
入库方式： OAI收割
来源：过程工程研究所
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