Effect of Sb dopant amount on the structure and electrocatalytic capability of Ti/Sb-SnO2 electrodes in the oxidation of 4-chlorophenol
文献类型：期刊论文
| 作者 | Kong Jiang-Tao; Shi Shao-Yuan; Zhu Xiu-Ping; Ni Jin-Ren |
| 刊名 | JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA
 |
| 出版日期 | 2007 |
| 卷号 | 19期号:11页码:1380-1386 |
| 关键词 | 4-chlorophenol cyclic voltammogram electrochemical oxidation Sb dopant Ti/Sb-SnO2 electrode |
| ISSN号 | 1001-0742 |
| 其他题名 | J. Environ. Sci. |
| 中文摘要 | Ti/Sb-SnO2 anodes were prepared by thermal decomposition to examine the influence of the amount of Sb dopant on the structure and electrocatalytic capability of the electrodes in the oxidation of 4-chlorophenol. The physicochemical properties of the Sb-SnO2 coating were markedly influenced by different amounts of Sb dopant. The electrodes, which contained 5% Sb dopant in the coating, presented a much more homogenous surface and much smaller mud-cracks, compared with Ti/Sb-SnO2 electrodes containing 10% or 15% Sb dopant, which exibited larger mud cracks and pores on the surface. However, the main microstructure remained unchanged with the addition of the Sb dopant. No new crystal phase was observed by X-ray diffraction (XRD). The electrochemical oxidation of 4-chlorophenol on the Ti/SnO2 electrode with 5% Sb dopant was inclined to electrochemical combustion; while for those containing more Sb dopant, intermediate species were accumulated. The electrodes with 5% Sb dopant showed the highest efficiency in the bulk electrolysis of 4-chlorophenol at a current density of 20 mA/cm(2) for 180 min; and the removal rates of 4-chlorophenol and COD were 51.0% and 48.9%, respectively. |
| 英文摘要 | Ti/Sb-SnO2 anodes were prepared by thermal decomposition to examine the influence of the amount of Sb dopant on the structure and electrocatalytic capability of the electrodes in the oxidation of 4-chlorophenol. The physicochemical properties of the Sb-SnO2 coating were markedly influenced by different amounts of Sb dopant. The electrodes, which contained 5% Sb dopant in the coating, presented a much more homogenous surface and much smaller mud-cracks, compared with Ti/Sb-SnO2 electrodes containing 10% or 15% Sb dopant, which exibited larger mud cracks and pores on the surface. However, the main microstructure remained unchanged with the addition of the Sb dopant. No new crystal phase was observed by X-ray diffraction (XRD). The electrochemical oxidation of 4-chlorophenol on the Ti/SnO2 electrode with 5% Sb dopant was inclined to electrochemical combustion; while for those containing more Sb dopant, intermediate species were accumulated. The electrodes with 5% Sb dopant showed the highest efficiency in the bulk electrolysis of 4-chlorophenol at a current density of 20 mA/cm(2) for 180 min; and the removal rates of 4-chlorophenol and COD were 51.0% and 48.9%, respectively. |
| WOS标题词 | Science & Technology ; Life Sciences & Biomedicine |
| 类目[WOS] | Environmental Sciences |
| 研究领域[WOS] | Environmental Sciences & Ecology |
| 关键词[WOS] | WASTE-WATER TREATMENT ; ELECTROCHEMICAL DEGRADATION ; THIN-FILMS ; CHLOROPHENOLS ; PHENOL ; ANTIMONY ; ANODES |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000251035600017 |
| 公开日期 | 2013-10-15 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/3357]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Peking Univ, Dept Environm Engn, Minist Educ China, Key Lab Water & Sediment Sci, Beijing 100871, Peoples R China 2.Chinese Acad Sci, Inst Process Engn, State Key Lab Biochem Engn, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kong Jiang-Tao,Shi Shao-Yuan,Zhu Xiu-Ping,et al. Effect of Sb dopant amount on the structure and electrocatalytic capability of Ti/Sb-SnO2 electrodes in the oxidation of 4-chlorophenol[J]. JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,2007,19(11):1380-1386. |
| APA | Kong Jiang-Tao,Shi Shao-Yuan,Zhu Xiu-Ping,&Ni Jin-Ren.(2007).Effect of Sb dopant amount on the structure and electrocatalytic capability of Ti/Sb-SnO2 electrodes in the oxidation of 4-chlorophenol.JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,19(11),1380-1386. |
| MLA | Kong Jiang-Tao,et al."Effect of Sb dopant amount on the structure and electrocatalytic capability of Ti/Sb-SnO2 electrodes in the oxidation of 4-chlorophenol".JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA 19.11(2007):1380-1386. |
入库方式： OAI收割
来源：过程工程研究所
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