Solution combustion synthesis and characterization of nanocrystalline La0.6Sr0.4Co0.2Fe0.8O3-delta cathode powders
文献类型:期刊论文
作者 | Lei Ze; Zhu Qing-Shan |
刊名 | ACTA PHYSICO-CHIMICA SINICA
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出版日期 | 2007-02-01 |
卷号 | 23期号:2页码:232-236 |
关键词 | LSCF cathode YSZ solid oxide fuel cell solution combustion method |
ISSN号 | 1000-6818 |
其他题名 | Acta Phys.-Chim. Sin. |
中文摘要 | La0.6Sr0.4Co0.2Fe0.8O3-delta (LSCF) precursor powder was prepared by a nitrate-glycine solution combustion method. The properties of LSCF powder were characterized by XRD, BET, FESEM, and dynamic laser scattering (DLS) method. The results showed that LSCF powder was in the perovskite structure with a specific surface area of 22.9 m(2) . g(-1) and an average particle size of 175 nm. The results of non-isothermal sintering tests suggested that LSCF powder possessed good low-temperature sintering activity. The cell Ni-YSZ/YSZ/LSCF (YSZ: yttria stabilized zirconia) with the cathode sintered at 800 degrees C for 2 h demonstrated excellent generation performance with the maximum power density of 0.97 W . cm(-2) and the power density of 0.83 W . cm(-2) at 0.7 V under operation at 700 degrees C. Low temperature processing of the interlayer-free LSCF cathode was beneficial to simplify the cell structure and manufacturing process and to improve the cell performance. |
英文摘要 | La0.6Sr0.4Co0.2Fe0.8O3-delta (LSCF) precursor powder was prepared by a nitrate-glycine solution combustion method. The properties of LSCF powder were characterized by XRD, BET, FESEM, and dynamic laser scattering (DLS) method. The results showed that LSCF powder was in the perovskite structure with a specific surface area of 22.9 m(2) . g(-1) and an average particle size of 175 nm. The results of non-isothermal sintering tests suggested that LSCF powder possessed good low-temperature sintering activity. The cell Ni-YSZ/YSZ/LSCF (YSZ: yttria stabilized zirconia) with the cathode sintered at 800 degrees C for 2 h demonstrated excellent generation performance with the maximum power density of 0.97 W . cm(-2) and the power density of 0.83 W . cm(-2) at 0.7 V under operation at 700 degrees C. Low temperature processing of the interlayer-free LSCF cathode was beneficial to simplify the cell structure and manufacturing process and to improve the cell performance. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Physical |
研究领域[WOS] | Chemistry |
关键词[WOS] | OXIDE FUEL-CELLS ; FERRITE-BASED PEROVSKITES ; PERFORMANCE ; SOFCS ; LAYER |
收录类别 | SCI |
原文出处 | |
语种 | 英语 |
WOS记录号 | WOS:000244264100018 |
公开日期 | 2013-10-15 |
版本 | 出版稿 |
源URL | [http://ir.ipe.ac.cn/handle/122111/3360] ![]() |
专题 | 过程工程研究所_研究所(批量导入) |
作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Key Lab Multiphase React, Beijing 100080, Peoples R China 2.Grad Univ, Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Lei Ze,Zhu Qing-Shan. Solution combustion synthesis and characterization of nanocrystalline La0.6Sr0.4Co0.2Fe0.8O3-delta cathode powders[J]. ACTA PHYSICO-CHIMICA SINICA,2007,23(2):232-236. |
APA | Lei Ze,&Zhu Qing-Shan.(2007).Solution combustion synthesis and characterization of nanocrystalline La0.6Sr0.4Co0.2Fe0.8O3-delta cathode powders.ACTA PHYSICO-CHIMICA SINICA,23(2),232-236. |
MLA | Lei Ze,et al."Solution combustion synthesis and characterization of nanocrystalline La0.6Sr0.4Co0.2Fe0.8O3-delta cathode powders".ACTA PHYSICO-CHIMICA SINICA 23.2(2007):232-236. |
入库方式: OAI收割
来源:过程工程研究所
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