Integrating Interactive Noble Metal Single-Atom Catalysts into Transition Metal Oxide Lattices
文献类型：期刊论文
| 作者 | Shan, Jieqiong; Ye, Chao; Zhu, Chongzhi; Dong, Juncai ; Xu, Wenjie; Chen, Ling; Jiao, Yan; Jiang, Yunling; Song, Li; Zhang, Yaning
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| 刊名 | Journal of the American Chemical Society
 |
| 出版日期 | 2022 |
| 卷号 | 144期号:50页码:23214-23222 |
| ISSN号 | 00027863 |
| DOI | 10.1021/jacs.2c11374 |
| 文献子类 | Article |
| 英文摘要 | Noble metals have broad prospects for catalytic applications yet are restricted to a few packing modes with limited structural flexibility. Here, we achieved geometric structure diversification of noble metals by integrating spatially correlated noble metal single atoms (e.g., Pt, Pd, and Ru) into the lattice of transition metal oxides (TMOs, e.g., Co3O4, Mn5O8, NiO, Fe2O3). The obtained noble metal single atoms exhibited distinct topologies (e.g., crs, fcu-hex-pcu, fcu, and bcu-x) from those of conventional metallic phases. For example, Pt single atoms with a crs topology (Ptcrs-Co3O4) are endowed with synergy of metal-metal and metal-support interactions. A quantitative relationship between various Pt topologies determined by TMO substrates and their electrocatalytic activities was established. We anticipate that this type of interactive single-atom catalysts can bridge the geometric, topological, and electronic structure gaps between the "close-packed" nanoparticles and isolated single atoms as two common categories of heterogeneous catalysts. © 2022 American Chemical Society. All rights reserved. |
| 电子版国际标准刊号 | 15205126 |
| 语种 | 英语 |
| WOS记录号 | WOS:000893528400001 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/299816]  |
| 专题 | 高能物理研究所_多学科研究中心 中国科学院高能物理研究所 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Shan, Jieqiong,Ye, Chao,Zhu, Chongzhi,et al. Integrating Interactive Noble Metal Single-Atom Catalysts into Transition Metal Oxide Lattices[J]. Journal of the American Chemical Society,2022,144(50):23214-23222. |
| APA | Shan, Jieqiong.,Ye, Chao.,Zhu, Chongzhi.,Dong, Juncai.,Xu, Wenjie.,...&Qiao, Shi-Zhang.(2022).Integrating Interactive Noble Metal Single-Atom Catalysts into Transition Metal Oxide Lattices.Journal of the American Chemical Society,144(50),23214-23222. |
| MLA | Shan, Jieqiong,et al."Integrating Interactive Noble Metal Single-Atom Catalysts into Transition Metal Oxide Lattices".Journal of the American Chemical Society 144.50(2022):23214-23222. |
入库方式： OAI收割
来源：高能物理研究所
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