Aqueous Electrolytes with Hydrophobic Organic Cosolvents for Stabilizing Zinc Metal Anodes
文献类型：期刊论文
| 作者 | Miao, Licheng; Wang, Renheng; Di, Shengli; Qian, Zhengfang; Zhang, Lei ; Xin, Wenli; Liu, Mengyu; Zhu, Zhiqiang; Chu, Shengqi; Du, Yi
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| 刊名 | ACS NANO
 |
| 出版日期 | 2022 |
| 卷号 | 16期号:6页码:9667-9678 |
| ISSN号 | 19360851 |
| DOI | 10.1021/acsnano.2c02996 |
| 文献子类 | Article |
| 英文摘要 | Rechargeable aqueous zinc (Zn) batteries are promising for large-energy storage because of their low cost, high safety, and environmental compatibility, but their implementation is hindered by the severe irreversibility of Zn metal anodes as exemplified by water-induced side reactions (H2evolution and Zn corrosion) and dendrite growth. Here, we find that the introduction of a hydrophobic carbonate cosolvent into a dilute aqueous electrolyte exhibits a much stronger ability to address the reversible issues facing Zn anodes than that with hydrophilic ones. Among the typical carbonates (ethylene carbonate, propylene carbonate, dimethyl carbonate, and diethyl carbonate (DEC)), DEC as the most hydrophobic additive enables the strongest breaking of water's H-bond network and replaces the solvating H2O in a Zn2+-solvation sheath, which significantly reduces the water activity and its decomposition. Additionally, DEC molecules preferentially adsorb onto the Zn surface to create an H2O-poor electrical double layer and render a dendrite-free Zn2+-plating behavior. The formulated hybrid 2 m Zn(OTf)2+ 7 m DEC electrolyte endows the Zn electrode with an ability to achieve high cycling stability (over 3500 h at 5 mA cm-2with 2.5 mA h cm-2) and supports the stable operation of Zn||V2O5·nH2O full battery. This efficient strategy with hydrophobic cosolvent suggests a promising direction for designing aqueous battery chemistries. © 2022 American Chemical Society. All rights reserved. |
| 电子版国际标准刊号 | 1936086X |
| 语种 | 英语 |
| WOS记录号 | WOS:000818982800001 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/299090]  |
| 专题 | 高能物理研究所_加速器中心 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Miao, Licheng,Wang, Renheng,Di, Shengli,et al. Aqueous Electrolytes with Hydrophobic Organic Cosolvents for Stabilizing Zinc Metal Anodes[J]. ACS NANO,2022,16(6):9667-9678. |
| APA | Miao, Licheng.,Wang, Renheng.,Di, Shengli.,Qian, Zhengfang.,Zhang, Lei.,...&Zhang, Ning.(2022).Aqueous Electrolytes with Hydrophobic Organic Cosolvents for Stabilizing Zinc Metal Anodes.ACS NANO,16(6),9667-9678. |
| MLA | Miao, Licheng,et al."Aqueous Electrolytes with Hydrophobic Organic Cosolvents for Stabilizing Zinc Metal Anodes".ACS NANO 16.6(2022):9667-9678. |
入库方式： OAI收割
来源：高能物理研究所
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