Study on the spectra of spruce lignin with chlorine dioxide oxidation
文献类型：期刊论文
| 作者 | Sun, Yong; Mang, Jin-ping; Yang, Gang; Li, Zuo-hu |
| 刊名 | SPECTROSCOPY AND SPECTRAL ANALYSIS
 |
| 出版日期 | 2007-08-01 |
| 卷号 | 27期号:8页码:1551-1554 |
| 关键词 | chlorine dioxide spruce lignin FTIR UV-visible FT-Raman NMR |
| ISSN号 | 1000-0593 |
| 其他题名 | Spectrosc. Spectr. Anal. |
| 中文摘要 | The Fourier transform infrared spectroscopy (FTIR), ultraviolet-Visible spectroscopy (UV-visible), Fourier transform Raman spectroscopy (FT-Raman), and nuclear magnetic resonance spectroscopy (H-1 NMR) were used to study the oxidation of spruce lignin by chloride dioxide. The results are as following: The selective oxidation of lignin by chlorine dioxide was obtained by spectroscopy study. FTIR showed that the characteristic absorbance peak of guaiacyl unit in the lignin structure was decreased after chloride dioxide oxidation, while the peaks of syringyl and para-hydroxyphenol disappeared after oxidation. The largely increased absorbance for the band around 1 720 cm(-1) corresponding to carbonyl stretching was achieved in the oxidized lignin. The ultraviolet-visible spectroscopy showed that the absorbance around 280 nm was largely reduced after the lignin had been oxidized. The H-1 NMR spectroscopy also showed the decrease of aromatic units and methoxyl group in the oxidized lignin. These indicated the formation of ester, or quinone derivatives when the lignin was selectively oxidized by chloride dioxide. |
| 英文摘要 | The Fourier transform infrared spectroscopy (FTIR), ultraviolet-Visible spectroscopy (UV-visible), Fourier transform Raman spectroscopy (FT-Raman), and nuclear magnetic resonance spectroscopy (H-1 NMR) were used to study the oxidation of spruce lignin by chloride dioxide. The results are as following: The selective oxidation of lignin by chlorine dioxide was obtained by spectroscopy study. FTIR showed that the characteristic absorbance peak of guaiacyl unit in the lignin structure was decreased after chloride dioxide oxidation, while the peaks of syringyl and para-hydroxyphenol disappeared after oxidation. The largely increased absorbance for the band around 1 720 cm(-1) corresponding to carbonyl stretching was achieved in the oxidized lignin. The ultraviolet-visible spectroscopy showed that the absorbance around 280 nm was largely reduced after the lignin had been oxidized. The H-1 NMR spectroscopy also showed the decrease of aromatic units and methoxyl group in the oxidized lignin. These indicated the formation of ester, or quinone derivatives when the lignin was selectively oxidized by chloride dioxide. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Spectroscopy |
| 研究领域[WOS] | Spectroscopy |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000249252000024 |
| 公开日期 | 2013-10-15 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/3436]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Biochem Engn, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Yong,Mang, Jin-ping,Yang, Gang,et al. Study on the spectra of spruce lignin with chlorine dioxide oxidation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2007,27(8):1551-1554. |
| APA | Sun, Yong,Mang, Jin-ping,Yang, Gang,&Li, Zuo-hu.(2007).Study on the spectra of spruce lignin with chlorine dioxide oxidation.SPECTROSCOPY AND SPECTRAL ANALYSIS,27(8),1551-1554. |
| MLA | Sun, Yong,et al."Study on the spectra of spruce lignin with chlorine dioxide oxidation".SPECTROSCOPY AND SPECTRAL ANALYSIS 27.8(2007):1551-1554. |
入库方式： OAI收割
来源：过程工程研究所
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