Single-Atom Iron Enables Strong Low-Triggering-Potential Luminol Cathodic Electrochemiluminescence
文献类型：期刊论文
| 作者 | Gu, Wenling; Wang, Xiaosi; Xi, Mengzhen; Wei, Xiaoqian; Jiao, Lei; Qin, Ying; Huang, Jiajia; Cui, Xiaowen; Zheng, Lirong ; Hu, Liuyong
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| 刊名 | Analytical Chemistry
 |
| 出版日期 | 2022 |
| 卷号 | 94期号:26页码:9459-9465 |
| ISSN号 | 00032700 |
| DOI | 10.1021/acs.analchem.2c01794 |
| 文献子类 | Article |
| 英文摘要 | The conventional cathodic electrochemiluminescence (ECL) always requires a more negative potential to trigger strong emission, which inevitably damages the bioactivity of targets and decreases the sensitivity and specificity. In this work, iron single-atom catalysts (Fe-N-C SACs) were employed as an efficient co-reaction accelerator for the first time to achieve the impressively cathodic emission of a luminol-H2O2ECL system at an ultralow potential. Benefiting from the distinct electronic structure, Fe-N-C SACs exhibit remarkable properties for the activation of H2O2to produce massive reactive oxygen species (ROS) under a negative scanning potential from 0 to -0.2 V. The ROS can oxidize the luminol anions into luminol anion radicals, avoiding the tedious electrochemical oxidation process of luminol. Then, the in situ-formed luminol anion radicals will directly react with ROS for the strong ECL emission. As a proof of concept, sensitive detection of the carcinoembryonic antigen was realized by glucose oxidase-mediated ECL immunoassay, shedding light on the superiority of SACs to construct efficient cathodic ECL systems with low triggering potential. © 2022 American Chemical Society. All rights reserved. |
| 电子版国际标准刊号 | 15206882 |
| 语种 | 英语 |
| WOS记录号 | WOS:000818866500001 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/299163]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Gu, Wenling,Wang, Xiaosi,Xi, Mengzhen,et al. Single-Atom Iron Enables Strong Low-Triggering-Potential Luminol Cathodic Electrochemiluminescence[J]. Analytical Chemistry,2022,94(26):9459-9465. |
| APA | Gu, Wenling.,Wang, Xiaosi.,Xi, Mengzhen.,Wei, Xiaoqian.,Jiao, Lei.,...&Zhu, Chengzhou.(2022).Single-Atom Iron Enables Strong Low-Triggering-Potential Luminol Cathodic Electrochemiluminescence.Analytical Chemistry,94(26),9459-9465. |
| MLA | Gu, Wenling,et al."Single-Atom Iron Enables Strong Low-Triggering-Potential Luminol Cathodic Electrochemiluminescence".Analytical Chemistry 94.26(2022):9459-9465. |
入库方式： OAI收割
来源：高能物理研究所
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