From Biomass to Functional Crystalline Diamond Nanothread: Pressure-Induced Polymerization of 2,5-Furandicarboxylic Acid
文献类型：期刊论文
| 作者 | Wang, Xuan,; Yang, Xin; Wang, Yida; Tang, Xingyu; Zheng, Haiyan; Zhang, Peijie; Gao, Dexiang; Che, Guangwei; Wang, Zijia; Guan, Aijiao |
| 刊名 | Journal of the American Chemical Society
 |
| 出版日期 | 2022 |
| 卷号 | 144期号:48页码:21837-21842 |
| ISSN号 | 00027863 |
| DOI | 10.1021/jacs.2c08914 |
| 文献子类 | Article |
| 英文摘要 | 2,5-Furandicarboxylic acid (FDCA) is one of the top-12 value-added chemicals from sugar. Besides the wide application in chemical industry, here we found that solid FDCA polymerized to form an atomic-scale ordered sp3-carbon nanothread (CNTh) upon compression. With the help of perfectly aligned π-πstacked molecules and strong intermolecular hydrogen bonds, crystalline poly-FDCA CNTh with uniform syn-configuration was obtained above 11 GPa, with the crystal structure determined by Rietveld refinement of the X-ray diffraction (XRD). The in situ XRD and theoretical simulation results show that the FDCA experienced continuous [4 + 2] Diels-Alder reactions along the stacking direction at the threshold C···C distance of ∼2.8 Å. Benefiting from the abundant carbonyl groups, the poly-FDCA shows a high specific capacity of 375 mAh g-1 as an anode material of a lithium battery with excellent Coulombic efficiency and rate performance. This is the first time a three-dimensional crystalline CNTh is obtained, and we demonstrated it is the hydrogen bonds that lead to the formation of the crystalline material with a unique configuration. It also provides a new method to move biomass compounds toward advanced functional carbon materials. © 2022 American Chemical Society. |
| 电子版国际标准刊号 | 15205126 |
| 语种 | 英语 |
| WOS记录号 | WOS:000890800200001 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/299819]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Wang, Xuan,,Yang, Xin,Wang, Yida,et al. From Biomass to Functional Crystalline Diamond Nanothread: Pressure-Induced Polymerization of 2,5-Furandicarboxylic Acid[J]. Journal of the American Chemical Society,2022,144(48):21837-21842. |
| APA | Wang, Xuan,.,Yang, Xin.,Wang, Yida.,Tang, Xingyu.,Zheng, Haiyan.,...&Mao, Ho-Kwang.(2022).From Biomass to Functional Crystalline Diamond Nanothread: Pressure-Induced Polymerization of 2,5-Furandicarboxylic Acid.Journal of the American Chemical Society,144(48),21837-21842. |
| MLA | Wang, Xuan,,et al."From Biomass to Functional Crystalline Diamond Nanothread: Pressure-Induced Polymerization of 2,5-Furandicarboxylic Acid".Journal of the American Chemical Society 144.48(2022):21837-21842. |
入库方式： OAI收割
来源：高能物理研究所
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