中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Advanced zirconia ceramics stabilized with yttria and magnesia: Structure and Vickers microhardness

文献类型:期刊论文

作者Rada, S.,; Zhang, J.; Rada, R.; Culea, E.
刊名Journal of the Mechanical Behavior of Biomedical Materials
出版日期2022
卷号134页码:105425
ISSN号17516161
DOI10.1016/j.jmbbm.2022.105425
文献子类Article
英文摘要The samples 8YSZ containing 70, 75, 80 mol% ZrO2 and other oxides were prepared by. a high temperature solid state reaction process. Using X-ray diffraction (XRD), Scanning Electron Microscopy (SEM) and spectroscopic methods were evaluated the effect of oxide addition on the properties of yttria-doped zirconia. X-ray data shows the formation of zirconia (Y-doped), YSZ and/or tetragonal zirconia crystalline phases in all samples. IR data indicate the stretching vibrations of the Si–O bonds from tetrahedral [SiO4] units and the stretching vibrations of the Fe–O bonds from [FeO6] structural units, respectively. EPR results indicate the destroying of the local ordering of the Fe+3 ion vicinities situated in the rhombic distorted octahedral geometries by the increasing of ZrO2 content in the host ceramic. The highest values of Vickers hardness were recorded for the ceramics containing 70 and 75 mol% ZrO2. This superior performance can be explained considering the presence of a smaller amount of monoclinic ZrO2 crystalline phase in the ceramic structure. The analysis of the X-ray Absorption Near Edge Structure (XANES) and Extended X-ray Absorption Fine Structure (EXAFS) data shows the presence of Fe+2 and Fe+3 ions. In the ceramics with higher ZrO2 contents the iron atoms adopt a randomly structure due to the highly distorted [FeO6] structural units and non-equivalent Fe–O distances in the first coordination shell. © 2022
电子版国际标准刊号18780180
语种英语
WOS记录号WOS:000863242200002
源URL[http://ir.ihep.ac.cn/handle/311005/299823]  
专题高能物理研究所_多学科研究中心
作者单位中国科学院高能物理研究所
推荐引用方式
GB/T 7714
Rada, S.,,Zhang, J.,Rada, R.,et al. Advanced zirconia ceramics stabilized with yttria and magnesia: Structure and Vickers microhardness[J]. Journal of the Mechanical Behavior of Biomedical Materials,2022,134:105425.
APA Rada, S.,,Zhang, J.,Rada, R.,&Culea, E..(2022).Advanced zirconia ceramics stabilized with yttria and magnesia: Structure and Vickers microhardness.Journal of the Mechanical Behavior of Biomedical Materials,134,105425.
MLA Rada, S.,,et al."Advanced zirconia ceramics stabilized with yttria and magnesia: Structure and Vickers microhardness".Journal of the Mechanical Behavior of Biomedical Materials 134(2022):105425.

入库方式: OAI收割

来源:高能物理研究所

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