Optimizing the Intercrystallite Connection of a Donor–Acceptor Conjugated Semiconductor Polymer by Controlling the Crystallization Rate via Temperature
文献类型：期刊论文
| 作者 | Li, HX; Liu, XY; Jin, TY; Zhao, KF; Zhang, Q ; He, CY; Yang, H; Chen, Y; Huang, JY; Yu, XH
|
| 刊名 | Macromolecular Rapid Communications
 |
| 出版日期 | 2022 |
| 卷号 | 43期号:16页码:2200084 |
| ISSN号 | 10221336 |
| DOI | 10.1002/marc.202200084 |
| 文献子类 | Article |
| 英文摘要 | The charge carrier transport of conjugated polymer thin film is mainly decided by the crystalline domain and intercrystallite connection. High-density tie-chain can provide an effective bridge between crystalline domains. Herein, the tie-chain connection behavior is optimized by decreasing the crystal region length (lc) and increasing the crystallization rate. Poly[4-(4,4-bis(2-octyldodecyl)-4H-cyclopenta[1,2-b:5,4-b′]dithiophen-2-yl)-alt-[1,2,5]-thiadiazolo[3,4-c]pyridine] (PCDTPT-ODD) is dissolved in nonpolar solvent isooctane and high ordered rod-like aggregations are formed. As the temperature increases, the changes in solution state and crystallization behavior lead to three different chain arrangement morphologies in the films: 1) at 25 °C, large and separated crystal regions are formed; 2) at 55 °C, small and well-connected crystal regions are formed due to faster crystallization rate and smaller nucleus size; 3) at 90 °C, the amorphous film is formed. Further results show that the film prepared at 55 °C has a smaller crystal region length (lc, 7.6 nm) and higher tie-chains content. Thus, the film exhibits the best device mobility of 2.3 × 10−3 cm2 V−1 s−1. This result shows the great influence of crystallization kinetics on the microstructure of conjugated polymer films and provides an effective way for the optimization of the intercrystallite tie-chain. © 2022 Wiley-VCH GmbH. |
| 电子版国际标准刊号 | 15213927 |
| 语种 | 英语 |
| WOS记录号 | WOS:000782377100001 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/299827]  |
| 专题 | 高能物理研究所_东莞分部 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Li, HX,Liu, XY,Jin, TY,et al. Optimizing the Intercrystallite Connection of a Donor–Acceptor Conjugated Semiconductor Polymer by Controlling the Crystallization Rate via Temperature[J]. Macromolecular Rapid Communications,2022,43(16):2200084. |
| APA | Li, HX.,Liu, XY.,Jin, TY.,Zhao, KF.,Zhang, Q.,...&Han, YC.(2022).Optimizing the Intercrystallite Connection of a Donor–Acceptor Conjugated Semiconductor Polymer by Controlling the Crystallization Rate via Temperature.Macromolecular Rapid Communications,43(16),2200084. |
| MLA | Li, HX,et al."Optimizing the Intercrystallite Connection of a Donor–Acceptor Conjugated Semiconductor Polymer by Controlling the Crystallization Rate via Temperature".Macromolecular Rapid Communications 43.16(2022):2200084. |
入库方式： OAI收割
来源：高能物理研究所
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