Boosting CO hydrogenation towards C2+ hydrocarbons over interfacial TiO2-x/Ni catalysts
文献类型：期刊论文
| 作者 | Xu, M; Qin, XT; Xu, Y ; Zhang, XC; Zheng, LR; Liu, JX; Wang, M; Liu, X; Ma, D
|
| 刊名 | NATURE COMMUNICATIONS
 |
| 出版日期 | 2022 |
| 卷号 | 13期号:1页码:6720 |
| DOI | 10.1038/s41467-022-34463-7 |
| 文献子类 | Article |
| 英文摘要 | Considerable attention has been drawn to tune the geometric and electronic structure of interfacial catalysts via modulating strong metal-support interactions (SMSI). Herein, we report the construction of a series of TiO2-x/Ni catalysts, where disordered TiO2-x overlayers immobilized onto the surface of Ni nanoparticles (similar to 20 nm) are successfully engineered with SMSI effect. The optimal TiO2-x/Ni catalyst shows a CO conversion of similar to 19.8% in Fischer-Tropsch synthesis (FTS) process under atmospheric pressure at 220 degrees C. More importantly, similar to 64.6% of the product is C2+ paraffins, which is in sharp contrast to the result of the conventional Ni catalyst with the main product being methane. A combination study of advanced electron microscopy, multiple in-situ spectroscopic characterizations, and density functional theory calculations indicates the presence of Ni delta-/TiO2-x interfacial sites, which could bind carbon atom strongly, inhibit methane formation and facilitate the C-C chain propagation, lead to the production of C2+ hydrocarbon on Ni surface. |
| 电子版国际标准刊号 | 2041-1723 |
| 语种 | 英语 |
| WOS记录号 | WOS:000879857400011 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/299967]  |
| 专题 | 高能物理研究所_多学科研究中心 高能物理研究所_粒子天体物理中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Xu, M,Qin, XT,Xu, Y,et al. Boosting CO hydrogenation towards C2+ hydrocarbons over interfacial TiO2-x/Ni catalysts[J]. NATURE COMMUNICATIONS,2022,13(1):6720. |
| APA | Xu, M.,Qin, XT.,Xu, Y.,Zhang, XC.,Zheng, LR.,...&Ma, D.(2022).Boosting CO hydrogenation towards C2+ hydrocarbons over interfacial TiO2-x/Ni catalysts.NATURE COMMUNICATIONS,13(1),6720. |
| MLA | Xu, M,et al."Boosting CO hydrogenation towards C2+ hydrocarbons over interfacial TiO2-x/Ni catalysts".NATURE COMMUNICATIONS 13.1(2022):6720. |
入库方式： OAI收割
来源：高能物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。