Synthesis, characterization and study on vibration spectra of potassium triborate
文献类型：期刊论文
| 作者 | Zhang Jin-ping; Sun Yong; Yang Gang; Li Zuo-hu |
| 刊名 | SPECTROSCOPY AND SPECTRAL ANALYSIS
 |
| 出版日期 | 2007-07-01 |
| 卷号 | 27期号:7页码:1351-1354 |
| 关键词 | potassium triborate synthesis characterization vibration spectra |
| ISSN号 | 1000-0593 |
| 其他题名 | Spectrosc. Spectr. Anal. |
| 中文摘要 | Potassium triborate was synthesized with potassium carbonate and boric acid by controlling suitable feed mixture ratio, reaction temperature and dehydration temperature in the self-designed boiling reactor. According to chemical analysis, the formula of the synthetics was monohydrate potassium triborate (KB3O5 - H2O). It's structure was characterized by XRD, FTIR, Raman and TG, and it was found by XRD analysis that the synthetics was amorphous solid. FTIR and Raman spectroscopy analysis show that three coordination 13(3) -O bond, four coordination BM -O bond, and hydroxy and triborate anions existed in the formula of the synthetics. Thermogravimetric (TG) analysis show that the groups which can lose mono-water existed in the formula of the synthetics, and structural formula of the synthetics was deduced as K[B3O4 (OH)2 ]. Vibration spectra of the synthetics were studied, including FTIR and Raman spectroscopy. Vibration absorption peaks of some main groups of the synthetics were investigated, including three coordination B-(3) -O bond and four coordination B-(4) -O bond that are the main existing forms of boron atoms in the synthetics as well as other groups, and each vibration absorption peak was assigned. |
| 英文摘要 | Potassium triborate was synthesized with potassium carbonate and boric acid by controlling suitable feed mixture ratio, reaction temperature and dehydration temperature in the self-designed boiling reactor. According to chemical analysis, the formula of the synthetics was monohydrate potassium triborate (KB3O5 - H2O). It's structure was characterized by XRD, FTIR, Raman and TG, and it was found by XRD analysis that the synthetics was amorphous solid. FTIR and Raman spectroscopy analysis show that three coordination 13(3) -O bond, four coordination BM -O bond, and hydroxy and triborate anions existed in the formula of the synthetics. Thermogravimetric (TG) analysis show that the groups which can lose mono-water existed in the formula of the synthetics, and structural formula of the synthetics was deduced as K[B3O4 (OH)2 ]. Vibration spectra of the synthetics were studied, including FTIR and Raman spectroscopy. Vibration absorption peaks of some main groups of the synthetics were investigated, including three coordination B-(3) -O bond and four coordination B-(4) -O bond that are the main existing forms of boron atoms in the synthetics as well as other groups, and each vibration absorption peak was assigned. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Spectroscopy |
| 研究领域[WOS] | Spectroscopy |
| 关键词[WOS] | RAMAN-SPECTROSCOPIC ANALYSIS ; AQUEOUS-SOLUTION ; BORATE ; CHLOROPINNOITE ; TRANSFORMATION ; DISSOLUTION ; FTIR |
| 收录类别 | SCI |
| 原文出处 | |
| 语种 | 英语 |
| WOS记录号 | WOS:000248697600026 |
| 公开日期 | 2013-10-15 |
| 版本 | 出版稿 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/3519]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | Chinese Acad Sci, Inst Proc Engn, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang Jin-ping,Sun Yong,Yang Gang,et al. Synthesis, characterization and study on vibration spectra of potassium triborate[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2007,27(7):1351-1354. |
| APA | Zhang Jin-ping,Sun Yong,Yang Gang,&Li Zuo-hu.(2007).Synthesis, characterization and study on vibration spectra of potassium triborate.SPECTROSCOPY AND SPECTRAL ANALYSIS,27(7),1351-1354. |
| MLA | Zhang Jin-ping,et al."Synthesis, characterization and study on vibration spectra of potassium triborate".SPECTROSCOPY AND SPECTRAL ANALYSIS 27.7(2007):1351-1354. |
入库方式： OAI收割
来源：过程工程研究所
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