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Catalytic Pyrolysis of Polyethylene for the Selective Production of Monocyclic Aromatics over the Zinc-Loaded ZSM-5 Catalyst

文献类型：期刊论文

作者Wang, Yazhuo1,2,3; Cheng, Leilei1,3,4; Gu, Jing1,3; Zhang, Yuyuan5; Wu, Jiahuan1,6; Yuan, Haoran1,2,3,4; Chen, Yong1,2,3,4
刊名ACS OMEGA
出版日期2022-01-25
卷号7期号:3页码:2752-2765
ISSN号2470-1343
DOI10.1021/acsomega.1c05401
通讯作者Yuan, Haoran(yuanhr@ms.giec.ac.cn)
英文摘要The transformation of waste plastics into value-added aromatics could incentivize better waste plastic management. The reported studies had low selectivity for monocyclic aromatics because more polycyclic aromatic hydrocarbons and carbon residues were generated. The effects of temperature, pressure, and catalyst on monocyclic aromatic selectivity were explored using a central composite design (CCD) followed by the response surface methodology (RSM) at a high ramp rate of 15 degrees C/min. The liquid product yield and selectivity to aromatic hydrocarbons were enhanced by regulating the acidic properties of the catalyst and processing parameters. The proportion of monocyclic aromatics in the liquid product was up to 90%, and the yield of monocyclic aromatics based on the reactant mass was 51% at the optimized condition. The carbon deposit production was low (only approximately 1%), which allowed higher liquid yields. In addition, the coupling mechanism of multiple factors on the depolymerization/aromatization reactions was proposed. This conversion of polyethylene into high-yield monocyclic aromatics provides a viable plastic recycling approach.
WOS关键词WASTE POLYETHYLENE ; PLASTIC WASTES ; ZEOLITE ; AROMATIZATION ; POLYPROPYLENE ; HYDROCARBONS ; RECOVERY ; FUELS
资助项目National Key Research and Development Program of China[2018YFC1901200] ; National Natural Science Foundation of China[51976223] ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou)[GML2019ZD0101] ; Guangdong Province Science and Technology Planning Project[2019B110210003]
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000772026100024
出版者AMER CHEMICAL SOC
资助机构National Key Research and Development Program of China ; National Natural Science Foundation of China ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) ; Guangdong Province Science and Technology Planning Project
源URL[http://ir.giec.ac.cn/handle/344007/35695]  
专题中国科学院广州能源研究所
通讯作者Yuan, Haoran
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
2.Nanjing Technol Univ, Sch Mech & Power Engn, Nanjing 211816, Peoples R China
3.Southern Marine Sci & Engn Guangdong Lab Guangzho, Guangzhou 511458, Peoples R China
4.Univ Sci & Technol China, Sch Energy Sci & Engn, Hefei 230026, Peoples R China
5.Foshan Univ, Coll Mat Sci & Energy Engn, Foshan 528000, Guangdong, Peoples R China
6.Shenzhen Gas Corp Ltd, Shenzhen 518000, Peoples R China
推荐引用方式
GB/T 7714		 Wang, Yazhuo,Cheng, Leilei,Gu, Jing,et al. Catalytic Pyrolysis of Polyethylene for the Selective Production of Monocyclic Aromatics over the Zinc-Loaded ZSM-5 Catalyst[J]. ACS OMEGA,2022,7(3):2752-2765.
APA Wang, Yazhuo.,Cheng, Leilei.,Gu, Jing.,Zhang, Yuyuan.,Wu, Jiahuan.,...&Chen, Yong.(2022).Catalytic Pyrolysis of Polyethylene for the Selective Production of Monocyclic Aromatics over the Zinc-Loaded ZSM-5 Catalyst.ACS OMEGA,7(3),2752-2765.
MLA Wang, Yazhuo,et al."Catalytic Pyrolysis of Polyethylene for the Selective Production of Monocyclic Aromatics over the Zinc-Loaded ZSM-5 Catalyst".ACS OMEGA 7.3(2022):2752-2765.

入库方式： OAI收割

来源：广州能源研究所

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