Highly Selective Hydrodeoxygenation of Lignin to Naphthenes over Three-Dimensional Flower-like Ni2P Derived from Hydrotalcite
文献类型：期刊论文
| 作者 | Jia, Zhichao2; Ji, Na2; Diao, Xinyong2; Li, Xinxin2,3; Zhao, Yujun4; Lu, Xuebin2; Liu, Qingling2; Liu, Caixia2; Chen, Guanyi2,5; Ma, Longlong1
|
| 刊名 | ACS CATALYSIS
 |
| 出版日期 | 2022-01-07 |
| 页码 | 19 |
| ISSN号 | 2155-5435 |
| 关键词 | lignin Ni2P catalyst NiAl-hydrotalcite hydrodeoxygenation naphthenes DFT calculations |
| DOI | 10.1021/acscatal.1c05495 |
| 通讯作者 | Ji, Na(jina@tju.edu.cn) ; Song, Chunfeng(chunfeng.song@tju.edu.cn) ; Li, Changzhi(licz@dicp.ac.cn) |
| 英文摘要 | A strategy for low-temperature synthesis of hydrotalcite-based nickel phosphide catalysts (Ni2P-Al2O3) with flower-like porous structures was proposed. The in situ reduction of red phosphorus at 500 degrees C enables Ni2P catalysts with small particle size and abundant active and acidic sites, which facilitate the activation of substrates and H-2. In the hydrodeoxygenation of guaiacol, a 100% conversion and 94.5% yield of cyclohexane were obtained over the Ni2P-Al2O3 catalyst under 5 MPa H2 at 250 degrees C for 3 h. Other lignin-derived phenolic compounds could also afford the corresponding alkanes with yields higher than 85%. Moreover, Ni2P-Al2O3 exhibited high hydrodeoxygenation activity in the deconstruction of more complex wood structures, including lignin oil and real lignin. Among the two different types of Ni sites of Ni(1) and Ni(2) in Ni2P, density functional theory (DFT) calculations showed that the Ni(2) site, highly exposed on the Ni2P-Al2O3 surface, possesses a stronger ability to break C-OH bonds during the hydrodeoxygenation of guaiacol in comparison with the Ni(1) site. |
| WOS关键词 | NICKEL PHOSPHIDE CATALYSTS ; GAS SHIFT REACTION ; PHENOLIC-COMPOUNDS ; BIO-OIL ; NI2P/SIO2 CATALYST ; MODEL-COMPOUND ; OXYGEN-REMOVAL ; PYROLYSIS OIL ; ACTIVE-SITES ; GUAIACOL |
| 资助项目 | National Key R&D Program of China[2018YFB1501500] ; National Natural Science Foundation of China[21975181] ; National Natural Science Foundation of China[22178258] ; Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development[E139kf0701] ; State Key Laboratory of Pulp and Paper Engineering (South China University of Technology)[202113] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000742749300001 |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development ; State Key Laboratory of Pulp and Paper Engineering (South China University of Technology) |
| 源URL | [http://ir.giec.ac.cn/handle/344007/35788]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Ji, Na; Song, Chunfeng; Li, Changzhi |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 2.Tianjin Univ, Sch Environm Sci & Engn, Tianjin Key Lab Biomass Wastes Utilizat, Tianjin 300350, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, CAS Key Lab Sci & Technol Appl Catalysis, Dalian 116023, Peoples R China 4.Tianjin Univ, Sch Chem Engn, Tianjin 300350, Peoples R China 5.Tianjin Univ Commerce, Tianjin 300134, Peoples R China 6.Zhejiang Univ, State Key Lab Clean Energy Utilizat, Hangzhou 310027, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jia, Zhichao,Ji, Na,Diao, Xinyong,et al. Highly Selective Hydrodeoxygenation of Lignin to Naphthenes over Three-Dimensional Flower-like Ni2P Derived from Hydrotalcite[J]. ACS CATALYSIS,2022:19. |
| APA | Jia, Zhichao.,Ji, Na.,Diao, Xinyong.,Li, Xinxin.,Zhao, Yujun.,...&Li, Changzhi.(2022).Highly Selective Hydrodeoxygenation of Lignin to Naphthenes over Three-Dimensional Flower-like Ni2P Derived from Hydrotalcite.ACS CATALYSIS,19. |
| MLA | Jia, Zhichao,et al."Highly Selective Hydrodeoxygenation of Lignin to Naphthenes over Three-Dimensional Flower-like Ni2P Derived from Hydrotalcite".ACS CATALYSIS (2022):19. |
入库方式： OAI收割
来源：广州能源研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。