Selective Production of 2-Butanol from Hydrogenolysis of Levulinic Acid Catalyzed by the Non-precious NiMn Bimetallic Catalyst
文献类型：期刊论文
| 作者 | Chen, Lungang2; Liu, Yong1,3,4; Gu, Canshuo2; Feng, Gang5; Zhang, Xinghua2 ; Liu, Jianguo2; Zhang, Qi2; Wang, Chenguang3; Ma, Longlong2
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| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
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| 出版日期 | 2021-11-22 |
| 卷号 | 9期号:46页码:15603-15611 |
| 关键词 | biomass levulinic acid 2-butanol hydrogenolysis DFT |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.1c05771 |
| 通讯作者 | Wang, Chenguang(wangcg@ms.giec.ac.cn) |
| 英文摘要 | Selective production of 2-butanol from levulinic acid (LA) hydro-genolysis over a non-precious catalyst is long desirable. However, the process requires the precious metal Ru, and the yield of 2-butanol was less than 65%. Herein, we prepared Ni-based bimetallic catalysts, among which the NiMn catalyst exhibited the highest efficiency and reached an 84.5% yield of 2-butanol at 100% LA conversion under optimal conditions. The electronic states and surface properties were characterized by various techniques such as X-ray diffraction, X-ray photoelectron spectroscopy, temperature-programmed desorption, temperatureprogrammed reduction, and scanning electron microscopy/transmission electron microscopy. The high efficiency of the NiMn catalyst was due to the synergy between Ni-0 and Mn2+ species, and the modified surface showed a high basicity and a high affinity to adsorb LA and LA-derived molecules with C = O or COOH. The high affinity of the NiMn catalyst was further confirmed by density functional theory calculations. |
| WOS关键词 | GAMMA-VALEROLACTONE ; CONVERSION ; CELLULOSE ; BIOMASS ; 2-METHYLTETRAHYDROFURAN ; HYDROGENATION ; BASICITY ; CHEMICALS |
| 资助项目 | National Key R&D Program of China[2019YFD1100601] ; National Natural Science Foundation of China[21878290] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000753951700025 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/35845]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Wang, Chenguang |
| 作者单位 | 1.Nanchang Univ, Key Lab Poyang Lake Environm & Resource Utilizat, Minist Educ, Nanchang 330031, Jiangxi, Peoples R China 2.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 4.Nanchang Univ, Sch Resources Environm & Chem Engn, Nanchang 330031, Jiangxi, Peoples R China 5.Nanchang Univ, Coll Chem, Inst Appl Chem, Key Lab Jiangxi Prov Environm & Energy Catalysis, Nanchang 330031, Jiangxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Lungang,Liu, Yong,Gu, Canshuo,et al. Selective Production of 2-Butanol from Hydrogenolysis of Levulinic Acid Catalyzed by the Non-precious NiMn Bimetallic Catalyst[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2021,9(46):15603-15611. |
| APA | Chen, Lungang.,Liu, Yong.,Gu, Canshuo.,Feng, Gang.,Zhang, Xinghua.,...&Ma, Longlong.(2021).Selective Production of 2-Butanol from Hydrogenolysis of Levulinic Acid Catalyzed by the Non-precious NiMn Bimetallic Catalyst.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,9(46),15603-15611. |
| MLA | Chen, Lungang,et al."Selective Production of 2-Butanol from Hydrogenolysis of Levulinic Acid Catalyzed by the Non-precious NiMn Bimetallic Catalyst".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 9.46(2021):15603-15611. |
入库方式： OAI收割
来源：广州能源研究所
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