Thermal behavior and kinetic study on the co-pyrolysis of biomass with polymer waste
文献类型：期刊论文
| 作者 | Yao, Zhitong2; Cai, Di3; Chen, Xinyang2; Sun, Yuhang2; Jin, Meiqing2; Qi, Wei4 ; Ding, Jiamin1
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| 刊名 | BIOMASS CONVERSION AND BIOREFINERY
 |
| 出版日期 | 2022-02-26 |
| 页码 | 12 |
| ISSN号 | 2190-6815 |
| 关键词 | Biomass Polymer Epoxy resin Co-pyrolysis Collaborative disposal |
| DOI | 10.1007/s13399-022-02480-7 |
| 通讯作者 | Yao, Zhitong(sxyzt@126.com) ; Qi, Wei(qiwei@ms.giec.ac.cn) |
| 英文摘要 | The intrinsic smaller hydrogen to carbon (H/C) ratio for lignocellulosic biomass significantly affects the yield and production of target products. Co-pyrolyzing of biomass with hydrogen-rich chemicals or raw materials offers an alternative pathway to improve the H/C ratio of feedstock and thus upgrade the bio-oils. In this work, the co-pyrolysis of rice husk (RH) with epoxy resin (ER) was attempted, and its kinetic was comprehensively studied using the model-free and model-fitting methods. The co-pyrolysis mechanism and kinetic compensation effects were probed as well. The thermogravimetric analysis indicated that the decomposition of RH-ER blend with a weight ratio of 1:1 can be divided into three stages with heating temperatures of 27-270, 270-500, and 500-850 degrees C and corresponding mass loss of 6.86, 49.30, and 5.60%, respectively. For the model-free models applied, the activation energies (Ea) displayed an uptrend in the degree of conversion (alpha) range of 0.05-0.2 and a downtrend in alpha range of 0.2-0.6. Comparing the six methods, the Ea values from Friedman method was significantly larger than those from other models. The Flynn-Wall-Ozawa (FWO) method was more reliable with higher correlation coefficients. The obtained Ea values gradually increased from 65.06 to 159.55 kJ/mol (0.05 <= alpha <= 0.20) and then decreased to 38.32 kJ/mol (0.2 < alpha <= 0.60). The Ea values calculated based on three-dimensional diffusion (Jander equation) was comparable to that from the FWO method and could be responsible for the co-pyrolysis mechanism for RH-ER blend. An excellent linear relationship lnA = 0.2058Ea - 2.63095 can be observed, indicating that the compensation effect existed between the Ea and lnA during RH and ER co-pyrolysis. The pre-exponential factor (A) was determined as 2.9E8 min(-1) using the average Ea value of 107.48 kJ/mol. Through this study, it is expected to promote the collaborative disposal of multisource solid waste. |
| WOS关键词 | MECHANISM ; CELLULOSE ; HEMICELLULOSE ; LIGNIN ; PINE |
| 资助项目 | Zhejiang Provincial Natural Science Foundation of China[LTY21B070002] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| 出版者 | SPRINGER HEIDELBERG |
| WOS记录号 | WOS:000761860500001 |
| 资助机构 | Zhejiang Provincial Natural Science Foundation of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/35869]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yao, Zhitong; Qi, Wei |
| 作者单位 | 1.Zhejiang Univ Taizhou, Res Inst, Taizhou 318000, Peoples R China 2.Hangzhou Dianzi Univ, Coll Mat & Environm Engn, Hangzhou 310018, Peoples R China 3.Beijing Univ Chem Technol, Ctr Biorefinery, Natl Energy R&D, Beijing 100029, Peoples R China 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yao, Zhitong,Cai, Di,Chen, Xinyang,et al. Thermal behavior and kinetic study on the co-pyrolysis of biomass with polymer waste[J]. BIOMASS CONVERSION AND BIOREFINERY,2022:12. |
| APA | Yao, Zhitong.,Cai, Di.,Chen, Xinyang.,Sun, Yuhang.,Jin, Meiqing.,...&Ding, Jiamin.(2022).Thermal behavior and kinetic study on the co-pyrolysis of biomass with polymer waste.BIOMASS CONVERSION AND BIOREFINERY,12. |
| MLA | Yao, Zhitong,et al."Thermal behavior and kinetic study on the co-pyrolysis of biomass with polymer waste".BIOMASS CONVERSION AND BIOREFINERY (2022):12. |
入库方式： OAI收割
来源：广州能源研究所
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