Synthesis of dihydrocapsaicin and dihydrocapsiate exclusively from lignocellulosic platform chemicals
文献类型：期刊论文
| 作者 | Li, Yan-Bing1,2; Guo, Hui-Ying1; Deng, Chen-Qiang1; Deng, Jin1 |
| 刊名 | GREEN ENERGY & ENVIRONMENT
 |
| 出版日期 | 2022-06-01 |
| 卷号 | 7期号:3页码:519-524 |
| 关键词 | Biorefinery Biomass Dihydrocapsaicin Hydrodeoxygenation Green chemistry |
| ISSN号 | 2096-2797 |
| DOI | 10.1016/j.gee.2020.11.001 |
| 通讯作者 | Deng, Jin(dengjin@ustc.edu.cn) |
| 英文摘要 | Biorefinery is pivotal to the sustainability of modern chemical industry. However, since biomass is oxygen-enriched, new and green chemical strategies are required for expanding the biomass derived chemical space. In this work, synthesis of natural products dihydrocapsaicin and dihydrocapsiate was achieved exclusively from lignocellulosic platform chemicals. Natural products dihydrocapsaicin and dihydrocapsiate were synthesized exclusively from lignocellulosic platform chemicals, using furfural (from hemicellulose) and methyl isopropyl ketone (from cellulose) through aldol condensation-hydrolysis-hydrodeoxygenation to synthesize 8-methylnonanoic acid and then combined with vanillin derivates (from lignin). This synthesis demonstrates the feasibility of constructing natural products entirely from renewable biomass platform through green processes. The utilization of inherent functional groups of biomass demonstrates their potential to open up chemical space. (C) 2020 Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co., Ltd. |
| WOS关键词 | WOLFF-KISHNER REDUCTION ; NATURAL-PRODUCTS ; CATALYTIC TRANSFORMATION ; CARBOXYLIC-ACIDS ; CAPSAICINOIDS ; HYDROGENOLYSIS ; HYDRODEOXYGENATION ; SCOPE ; PD/C |
| 资助项目 | National Natural Science Foundation of China[21875239] ; Fundamental Research Funds for the Central Universities[WK3530000004] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000780024500004 |
| 出版者 | KEAI PUBLISHING LTD |
| 资助机构 | National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities |
| 源URL | [http://ir.giec.ac.cn/handle/344007/36055]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Deng, Jin |
| 作者单位 | 1.Univ Sci & Technol China, Anhui Prov Key Lab Biomass Clean Energy, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Urban Pollutant Convers,IChem,Dept Ch, Hefei 230026, Anhui, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yan-Bing,Guo, Hui-Ying,Deng, Chen-Qiang,et al. Synthesis of dihydrocapsaicin and dihydrocapsiate exclusively from lignocellulosic platform chemicals[J]. GREEN ENERGY & ENVIRONMENT,2022,7(3):519-524. |
| APA | Li, Yan-Bing,Guo, Hui-Ying,Deng, Chen-Qiang,&Deng, Jin.(2022).Synthesis of dihydrocapsaicin and dihydrocapsiate exclusively from lignocellulosic platform chemicals.GREEN ENERGY & ENVIRONMENT,7(3),519-524. |
| MLA | Li, Yan-Bing,et al."Synthesis of dihydrocapsaicin and dihydrocapsiate exclusively from lignocellulosic platform chemicals".GREEN ENERGY & ENVIRONMENT 7.3(2022):519-524. |
入库方式： OAI收割
来源：广州能源研究所
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