Efficient electrocatalytic reduction of N-2 to ammonia at ambient conditions with municipal sludge-derived porous carbon codoped with multiple heteroatoms
文献类型：期刊论文
| 作者 | Deng, Lifang1,2,3; Wang, Lufeng3; Wei, Guoqiang1; Yuan, Haoran1,2,3 ; Xie, Jun1; Chen, Yong1,2,3
|
| 刊名 | ELECTROCHIMICA ACTA
 |
| 出版日期 | 2022-03-10 |
| 卷号 | 408页码:10 |
| ISSN号 | 0013-4686 |
| 关键词 | Municipal sludge Electrocatalytic reduction N 2 to ammonia Faraday efficiency |
| DOI | 10.1016/j.electacta.2022.139934 |
| 通讯作者 | Yuan, Haoran(yuanhaoran81@gmail.com) |
| 英文摘要 | Electrocatalytic reduction of N-2 to ammonia (NH3) at ambient conditions has attracted widespread attention, and revealing the mechanism has been a remarkably challenging problem for decades. This work developed a low-cost and efficient multiple heteroatom codoped porous carbon catalyst from municipal sludge (MSB-P), which demonstrated excellent electrochemical stability and selectivity for the electrochemical N-2 reduction reaction (N2RR). In 0.1 mol/L HCl solution, a high NH3 yield rate of 35.76 mu g.h(-1).mg(-1) cat. and an excellent Faraday Efficiency (FE) of 7.79% at-0.7 V vs. RHE (reversible hydrogen electrode) were obtained under ambient conditions. Furthermore, the electrocatalytic mechanism of MSB-P for N2RR was also revealed by in situ Fourier transform infrared spectroscopy (FTIR) data, and an associative route was identified. These findings provide an exciting new method for fabricating inexpensive and efficient carbon-based catalysts for production of NH3 at ambient conditions. (C)& nbsp;2022 Elsevier Ltd. All rights reserved. |
| WOS关键词 | HYDROGEN STORAGE ; GRAPHENE ; NITROGEN ; CATALYST ; DEGRADATION ; WATER |
| 资助项目 | Key-Area Research and Devel-opment Program of GuangDong Province[2019B110209003] ; Guangdong Basic and Applied Basic Research Foundation[2019A1515010928] ; Guangdong Basic and Applied Basic Research Foundation[2021B1515020068] ; Key Special Project for Introduced Talents Team of Southern Marine Science and En-gineering Guangdong Laboratory (Guangzhou)[GML2019ZD0101] ; Guangdong Province Science and Technology Planning Project[2019B1102100 03] |
| WOS研究方向 | Electrochemistry |
| 语种 | 英语 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| WOS记录号 | WOS:000780756600011 |
| 资助机构 | Key-Area Research and Devel-opment Program of GuangDong Province ; Guangdong Basic and Applied Basic Research Foundation ; Key Special Project for Introduced Talents Team of Southern Marine Science and En-gineering Guangdong Laboratory (Guangzhou) ; Guangdong Province Science and Technology Planning Project |
| 源URL | [http://ir.giec.ac.cn/handle/344007/36185]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yuan, Haoran |
| 作者单位 | 1.South China Agr Univ, Guangdong Engn Technol Res Ctr Agr & Forestry Bio, Key Lab Energy Plants Resource & Utilizat, Inst Biomass Engn,Minist Agr & Rural Affairs, Guangzhou 510642, Peoples R China 2.Southern Marine Sci & Engn Guangdong Lab Guangzho, Guangzhou 510650, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 |
Deng, Lifang,Wang, Lufeng,Wei, Guoqiang,et al. Efficient electrocatalytic reduction of N-2 to ammonia at ambient conditions with municipal sludge-derived porous carbon codoped with multiple heteroatoms [J]. ELECTROCHIMICA ACTA,2022,408:10. |
| APA |
Deng, Lifang,Wang, Lufeng,Wei, Guoqiang,Yuan, Haoran,Xie, Jun,&Chen, Yong.(2022). Efficient electrocatalytic reduction of N-2 to ammonia at ambient conditions with municipal sludge-derived porous carbon codoped with multiple heteroatoms .ELECTROCHIMICA ACTA,408,10. |
| MLA |
Deng, Lifang,et al." Efficient electrocatalytic reduction of N-2 to ammonia at ambient conditions with municipal sludge-derived porous carbon codoped with multiple heteroatoms ".ELECTROCHIMICA ACTA 408(2022):10. |
入库方式： OAI收割
来源：广州能源研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。