Zinc chloride-activated micro-mesoporous carbon material derived from energy grass and its electrocatalytic performance toward oxygen reduction reaction
文献类型：期刊论文
| 作者 | Liu, Weidong1,2; Yang, Juntao1,2; Liu, Shanjian1; Yi, Weiming1; Sun, Yongming2 ; Yang, Gaixiu2
|
| 刊名 | JOURNAL OF ENERGY STORAGE
 |
| 出版日期 | 2022-02-01 |
| 卷号 | 46页码:7 |
| 关键词 | Biomass Chemical activation Porous structure Oxygen reduction reaction Electrocatalyst |
| DOI | 10.1016/j.est.2021.103697 |
| 通讯作者 | Liu, Shanjian(liushanjian08@163.com) ; Yang, Gaixiu(yanggx@ms.giec.ac.cn) |
| 英文摘要 | Biomass is an ideal candidate for the preparation of nano-carbon catalyst because of its inherent porous structure and abundant heteroatoms. However, the rational design of the structure remains challenging. In this work, a biomass-based carbon material with micro-meso porous structure, high specific surface area and abundant active sites was fabricated by the activation of ZnCl2. The correct additive amount of activator is essential to affect the surface composition and structures. In order to achieve a high-performance carbon catalyst, the activation mechanism of ZnCl2 for the pyrolysis of elephant grass (EG) was also investigated. The electrochemical measurements revealed that the obtained carbon catalyst with an EG:ZnCl2 ratio of 1:1 showed superior electrocatalytic properties for ORR over a wide pH range, due to the its large surface area (1119.83 m(2)g(-1)), hierarchical structure and abundant N content (pyridine-N/graphite-N/pyrrolic-N). The abundant micro/mesoporous structure provides accessible channels for the transport of O-2, H2O and intermediate products (OH*, O-2*). This study provides a simple and low-cost method for the effective conversion of biomass to nano-carbon materials, which shows great application potential for fuel cells. |
| WOS关键词 | NITROGEN-DOPED GRAPHENE ; ELECTRON-TRANSFER ; CATALYST ; BIOMASS ; SULFUR |
| 资助项目 | National Natural Science Foundation of China[51806224] ; National Natural Science Foundation of China[51606113] ; Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development[E039kf0701] ; Natural Science Foundation of Guangdong Province of China[2019A1515011971] ; Natural Science Foundation of Guangdong Province of China[2017A030310280] ; Youth Innovation Promotion Association CAS[2020345] |
| WOS研究方向 | Energy & Fuels |
| 语种 | 英语 |
| WOS记录号 | WOS:000779412400003 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China ; Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development ; Natural Science Foundation of Guangdong Province of China ; Youth Innovation Promotion Association CAS |
| 源URL | [http://ir.giec.ac.cn/handle/344007/36254]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Liu, Shanjian; Yang, Gaixiu |
| 作者单位 | 1.Shandong Univ Technol, Sch Agr Engn & Food Sci, Zibo 255000, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Weidong,Yang, Juntao,Liu, Shanjian,et al. Zinc chloride-activated micro-mesoporous carbon material derived from energy grass and its electrocatalytic performance toward oxygen reduction reaction[J]. JOURNAL OF ENERGY STORAGE,2022,46:7. |
| APA | Liu, Weidong,Yang, Juntao,Liu, Shanjian,Yi, Weiming,Sun, Yongming,&Yang, Gaixiu.(2022).Zinc chloride-activated micro-mesoporous carbon material derived from energy grass and its electrocatalytic performance toward oxygen reduction reaction.JOURNAL OF ENERGY STORAGE,46,7. |
| MLA | Liu, Weidong,et al."Zinc chloride-activated micro-mesoporous carbon material derived from energy grass and its electrocatalytic performance toward oxygen reduction reaction".JOURNAL OF ENERGY STORAGE 46(2022):7. |
入库方式： OAI收割
来源：广州能源研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。