Biomass-derived 2-methyltetrahydrofuran platform: a focus on precious and non-precious metal-based catalysts for the biorefinery
文献类型：期刊论文
| 作者 | Alorku, Kingdom1,2,3,4; Shen, Chen1,2,3,4; Li, Yuhang1,2,3,4; Xu, Ying1,2,3,4 ; Wang, Chenguang1,2,3,4; Liu, Qiying1,2,3,4
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| 刊名 | GREEN CHEMISTRY
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| 出版日期 | 2022-06-06 |
| 卷号 | 24期号:11页码:4201-4236 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/d2gc00759b |
| 通讯作者 | Liu, Qiying(liuqy@ms.giec.ac.cn) |
| 英文摘要 | Biomass conversion to platform chemicals, value-added chemicals, or fuels is important because it provides a sustainable or carbon-neutral alternative to fossil fuel feedstocks. During the conversion of biomass into useful chemicals or fuels, the recalcitrant cell wall of the biomass feedstock is first broken down into useful sugars that can be converted over chemical catalysts or enzymes. Converting sugars to biofuels or useful chemicals over biological enzymes can be costly. Therefore, current research is more aligned with the employment of functionalized metal catalysts, which are preferred owing to their stability, recyclability, and easy separability. 2-Methyltetrahydrofuran (MTHF) is a vital sugar-derived platform chemical that is used as a green solvent, fuel additive, or as the starting material for synthesizing downstream chemicals such as dienes, pentane, and 2-pentanone. Based on MTHF formation from sugar derivatives and its further conversion over catalysts, this review discusses the challenges faced during the conversion of biomass to MTHF on precious and non-precious metal-based catalysts and the successive catalytic conversion of MTHF as a platform chemical to value-added downstream chemicals. Finally, the conclusions and perspectives for this catalytic biorefinery are proposed with future recommendations. |
| WOS关键词 | VAPOR-PHASE HYDROGENATION ; REVERSIBLE DEHYDROGENATION-HYDROGENATION ; HIGHLY EFFICIENT HYDROGENATION ; AQUEOUS LEVULINIC ACID ; IN-SITU HYDROGENATION ; GAMMA-VALEROLACTONE ; SELECTIVE HYDROGENATION ; FURFURYL ALCOHOL ; ELECTROCATALYTIC HYDROGENATION ; TETRAHYDROFURFURYL ALCOHOL |
| 资助项目 | National Science Foundation of China[51976220] ; National Key R&D Program of China[2019YFC1905303] ; USTC and ANSO scholarship for Young Talents |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000797622900001 |
| 资助机构 | National Science Foundation of China ; National Key R&D Program of China ; USTC and ANSO scholarship for Young Talents |
| 源URL | [http://ir.giec.ac.cn/handle/344007/36518]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Liu, Qiying |
| 作者单位 | 1.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 2.Univ Sci & Technol China, 96 Jinzhai Rd Baohe Dist, Hefei 230026, Anhui, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, 2 Nengyuan Rd, Guangzhou 510640, Peoples R China 4.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Alorku, Kingdom,Shen, Chen,Li, Yuhang,et al. Biomass-derived 2-methyltetrahydrofuran platform: a focus on precious and non-precious metal-based catalysts for the biorefinery[J]. GREEN CHEMISTRY,2022,24(11):4201-4236. |
| APA | Alorku, Kingdom,Shen, Chen,Li, Yuhang,Xu, Ying,Wang, Chenguang,&Liu, Qiying.(2022).Biomass-derived 2-methyltetrahydrofuran platform: a focus on precious and non-precious metal-based catalysts for the biorefinery.GREEN CHEMISTRY,24(11),4201-4236. |
| MLA | Alorku, Kingdom,et al."Biomass-derived 2-methyltetrahydrofuran platform: a focus on precious and non-precious metal-based catalysts for the biorefinery".GREEN CHEMISTRY 24.11(2022):4201-4236. |
入库方式： OAI收割
来源：广州能源研究所
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