Selective Hydrogenolysis of 5-Hydroxymethylfurfural to 2-Hexanol over Au/ZrO2 Catalysts
文献类型：期刊论文
| 作者 | Hu, Xiaohong1,2,3; Li, Zhijian1,2,4; Wang, Haiyong1,2; Xin, Haosheng1,2,3; Li, Song1,2; Wang, Chenguang1,2,4; Ma, Longlong1,2,4 ; Liu, Qiying1,2,4
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| 刊名 | CHEMSUSCHEM
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| 出版日期 | 2022-05-13 |
| 页码 | 13 |
| ISSN号 | 1864-5631 |
| 关键词 | 2-hexanol 5-hydroxymethylfurfural biomass conversion heterogeneous catalysis hydrogenolysis |
| DOI | 10.1002/cssc.202200092 |
| 通讯作者 | Ma, Longlong(mall@ms.giec.ac.cn) ; Liu, Qiying(liuqy@ms.giec.ac.cn) |
| 英文摘要 | 2-Hexanol (2-HOL) is a versatile biomass-derived platform molecule for synthesis of liquid transportation fuels, lubricants, or detergents. Herein, a one-step preparation of 2-HOL using 5-hydroxymethylfurfural (HMF) as a substrate was reported for the first time. Several Au-based catalysts supported on different metal oxides were prepared to explore the relationship between carrier and catalytic activity. The results showed that the highest 2-HOL yield of 65.8 % was obtained at complete HMF conversion over the 5 %Au/ZrO2 catalyst. The 5 %Au/ZrO2 catalyst exhibited excellent durability after five consecutive recycling runs, while confirming its remarkable ring-opening hydrogenolysis on other biomass-derived furanics, furfural, with a total yield of 1-pentanol and 2-pentanol of 67.4 %. The distinguished ring-opening hydrogenolysis performance of the Au/ZrO2 catalyst originated from a synergistic effect between the interfacial Au-O-Zr oxygen vacancies-induced Lewis acidic sites (activating C-OH/C=O bonds) and metallic Au (activating H-2). This work provides a possibility for producing 2-HOL from HMF with high yield, expanding the sustainable application of lignocellulosic biomass. |
| WOS关键词 | GAS SHIFT REACTION ; FORMIC-ACID ; 2,5-FURANDICARBOXYLIC ACID ; DIKETONE DERIVATIVES ; CO OXIDATION ; CONVERSION ; GOLD ; AU ; BIOMASS ; 2,5-DIMETHYLFURAN |
| 资助项目 | National Key Research and Development Program of China[2018YFB1501402] ; National Natural Science Foundation of China[51976220] ; R & D Plan of Key Fields in Guangdong Province[2020B1111570001] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000795962900001 |
| 资助机构 | National Key Research and Development Program of China ; National Natural Science Foundation of China ; R & D Plan of Key Fields in Guangdong Province |
| 源URL | [http://ir.giec.ac.cn/handle/344007/36546]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Ma, Longlong; Liu, Qiying |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Guangdong Prov Key Lab New & Renewable Energy Res, CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Univ Sci & Technol China, Hefei 230026, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Xiaohong,Li, Zhijian,Wang, Haiyong,et al. Selective Hydrogenolysis of 5-Hydroxymethylfurfural to 2-Hexanol over Au/ZrO2 Catalysts[J]. CHEMSUSCHEM,2022:13. |
| APA | Hu, Xiaohong.,Li, Zhijian.,Wang, Haiyong.,Xin, Haosheng.,Li, Song.,...&Liu, Qiying.(2022).Selective Hydrogenolysis of 5-Hydroxymethylfurfural to 2-Hexanol over Au/ZrO2 Catalysts.CHEMSUSCHEM,13. |
| MLA | Hu, Xiaohong,et al."Selective Hydrogenolysis of 5-Hydroxymethylfurfural to 2-Hexanol over Au/ZrO2 Catalysts".CHEMSUSCHEM (2022):13. |
入库方式： OAI收割
来源：广州能源研究所
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