Kinetics modeling of co-pyrolytic decomposition of binary system of cellulose, xylan and lignin
文献类型：期刊论文
| 作者 | Fan, Honggang1,2,4; Gu, Jing1,2,4; Wang, Yazhuo1,2,3,4 ; Yuan, Haoran1,2,4; Chen, Yong1,2,3,4
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| 刊名 | JOURNAL OF THE ENERGY INSTITUTE
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| 出版日期 | 2022-06-01 |
| 卷号 | 102页码:278-288 |
| ISSN号 | 1743-9671 |
| 关键词 | Pyrolysis kinetics Distributed activation energy model (DAEM) Biomass components Double-Gaussian-DAEM Three-Gaussian-DAEM |
| DOI | 10.1016/j.joei.2022.03.012 |
| 通讯作者 | Yuan, Haoran(yuanhr@ms.giec.ac.cn) |
| 英文摘要 | The co-pyrolysis kinetics of a binary system of cellulose, xylan and lignin was investigated by means of a thermogravimetric analyzer based on distributed activation energy model (DAEM). Synergistic effects were found in the co-pyrolysis of the binary system, resulting in a shift toward lower decomposition temperature and different decomposition rate. In terms of the kinetic mechanism, the results showed that the fitting performance of double-Gaussian-DAEM (DG-DAEM) was poor for the conversion rate curves and that the weighting factor cannot accurately reflect the reaction contribution of components in the binary system. Then, the predictions of three-Gaussian-DAEM (TG-DAEM) were well matched to the experimental curves, indicating that TG-DAEM was more suitable than DG-DAEM for describing the co-pyrolysis process of a binary system. The weighting factors in TG-DAEM represented the reaction contribution of each decomposition stage in the co-pyrolysis process, which was consistent with each peak in the DTG profiles. Excellent prediction performance was verified for TG-DAEM to predict the thermal behaviors at different heating rates. |
| WOS关键词 | ACTIVATION-ENERGY MODEL ; THERMAL-DECOMPOSITION ; PRODUCTS ; HEMICELLULOSE ; BEHAVIOR ; DAEM |
| 资助项目 | Key-Area Research and Develop-ment Program of Guangdong Province[2020B1111380001] ; Key Spe-cial Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou)[GML2019ZD0101] ; National Natural Science Foundation of China[51976223] ; Guangdong Basic and Applied Basic Research Foundation[2021B1515020068] |
| WOS研究方向 | Energy & Fuels |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCI LTD |
| WOS记录号 | WOS:000797733100006 |
| 资助机构 | Key-Area Research and Develop-ment Program of Guangdong Province ; Key Spe-cial Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) ; National Natural Science Foundation of China ; Guangdong Basic and Applied Basic Research Foundation |
| 源URL | [http://ir.giec.ac.cn/handle/344007/36552]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yuan, Haoran |
| 作者单位 | 1.Southern Marine Sci & Engn Guangdong Lab Guangzhou, Guangzhou 511458, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.Nanjing Tech Univ, Nanjing 211816, Peoples R China 4.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fan, Honggang,Gu, Jing,Wang, Yazhuo,et al. Kinetics modeling of co-pyrolytic decomposition of binary system of cellulose, xylan and lignin[J]. JOURNAL OF THE ENERGY INSTITUTE,2022,102:278-288. |
| APA | Fan, Honggang,Gu, Jing,Wang, Yazhuo,Yuan, Haoran,&Chen, Yong.(2022).Kinetics modeling of co-pyrolytic decomposition of binary system of cellulose, xylan and lignin.JOURNAL OF THE ENERGY INSTITUTE,102,278-288. |
| MLA | Fan, Honggang,et al."Kinetics modeling of co-pyrolytic decomposition of binary system of cellulose, xylan and lignin".JOURNAL OF THE ENERGY INSTITUTE 102(2022):278-288. |
入库方式： OAI收割
来源：广州能源研究所
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