N/S Co-doped microporous carbon derived from PSSH-Melamine salt solution as cathode host for Lithium-Selenium batteries
文献类型：期刊论文
| 作者 | Xia, Qi1,2; Hu, Jinlong2; Chen, Qingqing1,2; Zhang, Lingzhi2
|
| 刊名 | JOURNAL OF COLLOID AND INTERFACE SCIENCE
 |
| 出版日期 | 2022-03-15 |
| 卷号 | 610页码:643-652 |
| ISSN号 | 0021-9797 |
| 关键词 | Micropore carbon Heteroatom doping Electrolyte Lithium-selenium batteries |
| DOI | 10.1016/j.jcis.2021.11.106 |
| 通讯作者 | Zhang, Lingzhi(lzzhang@ms.giec.ac.cn) |
| 英文摘要 | Selenium cathode attracts great attention due to its high theoretical volumetric capacity and better electrical conductivity than sulfur cathode. Herein, N/S co-doped microporous carbon (NS-K-PC) is designed and prepared as Se host by a spray drying process of the poly(styrenesulfonic acid)-melamine salt solution followed by carbonization and activation process. The as-prepared NS-K-PC shows a very high micropore contribution of 94.8% in the total surface area, and a total N/S heteroatom doping level of 2.5 wt% in the carbon matrix. The NS-K-PC/Se cathode delivers a high reversible capacity of 499.2 mA h g(-1) at 0.1C, superior rate capacity of 324 mA h g(-1) at 8C, and great cycling stability with a capacity decay of 0.081% per cycle over 500 cycles at 1C. Additionally, a comparative study demonstrates that NS-K-PC/Se cathode with the carbonate-based electrolytes exhibit better cycling stability than those with ether-based electrolytes primarily resulted from a direct solid-solid conversion of Se to Li2Se bypassing the formation of soluble polyselenides. (C) 2021 Elsevier Inc. All rights reserved. |
| WOS关键词 | HIERARCHICALLY POROUS CARBON ; LI-SE ; ION BATTERIES ; LONG-LIFE ; PERFORMANCE ; COMPOSITE ; GRAPHENE ; POLYSULFIDES ; TEMPERATURE ; NANOFIBERS |
| 资助项目 | National Natural Science Foundation of China[22075288] ; Guangzhou Science and Technology Plan Project[202102020323] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| WOS记录号 | WOS:000796258900001 |
| 资助机构 | National Natural Science Foundation of China ; Guangzhou Science and Technology Plan Project |
| 源URL | [http://ir.giec.ac.cn/handle/344007/36570]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhang, Lingzhi |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xia, Qi,Hu, Jinlong,Chen, Qingqing,et al. N/S Co-doped microporous carbon derived from PSSH-Melamine salt solution as cathode host for Lithium-Selenium batteries[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2022,610:643-652. |
| APA | Xia, Qi,Hu, Jinlong,Chen, Qingqing,&Zhang, Lingzhi.(2022).N/S Co-doped microporous carbon derived from PSSH-Melamine salt solution as cathode host for Lithium-Selenium batteries.JOURNAL OF COLLOID AND INTERFACE SCIENCE,610,643-652. |
| MLA | Xia, Qi,et al."N/S Co-doped microporous carbon derived from PSSH-Melamine salt solution as cathode host for Lithium-Selenium batteries".JOURNAL OF COLLOID AND INTERFACE SCIENCE 610(2022):643-652. |
入库方式： OAI收割
来源：广州能源研究所
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