Nitrogen transfer mechanism research on the co- pyrolysis macroalgae with polyethylene
文献类型：期刊论文
| 作者 | Yang, Xuping1; Jiang, Ding1; Cheng, Xiaoxue1; Marrakchi, Fatma1; Yuan, Chuan1,2; He, Zhixia4; Wang, Shuang1; Zheng, Anqing3
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| 刊名 | SUSTAINABLE ENERGY TECHNOLOGIES AND ASSESSMENTS
 |
| 出版日期 | 2022-06-01 |
| 卷号 | 51页码:13 |
| 关键词 | Enteromorpha prolifera Polyethylene Pyrolysis Nitrogen conversion Density functional theory |
| ISSN号 | 2213-1388 |
| DOI | 10.1016/j.seta.2021.101886 |
| 通讯作者 | Wang, Shuang(alexjuven@ujs.edu.cn) ; Zheng, Anqing(zhengaq@ms.giec.ac.cn) |
| 英文摘要 | This study unveiled the effect of co-pyrolysis and nitrogen transformation characteristics of macroalgae (Enter-omorpha prolifera (EP)) and waste plastics (polyethylene) by using Py-GC/MS experiment and density functional theory (DFT). The possible reaction pathways were designed by using composition and pyrolysis intermediates of EP including amino acids and cyclic acylamide as model compounds, respectively. Subsequently, the mechanism of nitrogen transformation during the pyrolysis of EP and the synergistic mechanism of co-pyrolysis with polyethylene (PE) were revealed by DFT. Py-GC/MS results showed that the nitrogen-containing products of EP pyrolysis were mainly Sarcosine, Imidazole, and (2E)-3-(2-Amino-1H-imidazol-5-yl) acrylic acid, and the co pyrolysis products were urea and cadaverine. Co-pyrolysis is beneficial to decreased the species and quantities of N-containing compounds, and the relative content of nitrogen-containing compounds decreased from 7.91% to 3.53%. The DFT results also verified the rationality of each possible pathway using the quantum chemistry calculation and through analysis of the activation energy (delta G*), the reaction heat (delta G) and the reaction enthalpy change (delta H). This study confirmed that there is a synergistic effect in the co-pyrolysis process of EP and PE in which the hydrogen radicals provided by PE can reduce the reaction energy barrier and then promote the mechanism of nitrogen during the pyrolysis process. |
| WOS关键词 | HIGH-DENSITY POLYETHYLENE ; LIGNOCELLULOSIC BIOMASS ; MICROALGAE ; OIL ; PROTEINS ; NITROGEN ; CHAR ; NOX ; HCN |
| 资助项目 | Key Research and Development Project of Jiangsu Province[BE2019009-4] |
| WOS研究方向 | Science & Technology - Other Topics ; Energy & Fuels |
| 语种 | 英语 |
| WOS记录号 | WOS:000789646300006 |
| 出版者 | ELSEVIER |
| 资助机构 | Key Research and Development Project of Jiangsu Province |
| 源URL | [http://ir.giec.ac.cn/handle/344007/36831]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Wang, Shuang; Zheng, Anqing |
| 作者单位 | 1.Jiangsu Univ, Sch Energy & Power Engn, Zhenjiang 212013, Jiangsu, Peoples R China 2.Jiangsu Univ, Sch Agr Engn, Zhenjiang 212013, Jiangsu, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou, Peoples R China 4.Jiangsu Univ, Inst Energy Res, Zhenjiang 212013, Jiangsu, Peoples R China |
| 推荐引用方式 GB/T 7714 |
Yang, Xuping,Jiang, Ding,Cheng, Xiaoxue,et al. Nitrogen transfer mechanism research on the co- pyrolysis macroalgae with polyethylene [J]. SUSTAINABLE ENERGY TECHNOLOGIES AND ASSESSMENTS,2022,51:13. |
| APA |
Yang, Xuping.,Jiang, Ding.,Cheng, Xiaoxue.,Marrakchi, Fatma.,Yuan, Chuan.,...&Zheng, Anqing.(2022). Nitrogen transfer mechanism research on the co- pyrolysis macroalgae with polyethylene .SUSTAINABLE ENERGY TECHNOLOGIES AND ASSESSMENTS,51,13. |
| MLA |
Yang, Xuping,et al." Nitrogen transfer mechanism research on the co- pyrolysis macroalgae with polyethylene ".SUSTAINABLE ENERGY TECHNOLOGIES AND ASSESSMENTS 51(2022):13. |
入库方式： OAI收割
来源：广州能源研究所
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