Electroplating sludge-derived magnetic copper-containing catalysts for selective hydrogenation of bio-based furfural
文献类型：期刊论文
| 作者 | Xiao, Yaoxin1,2; Zhang, Jun2,3,4,5; Zhu, Lingjun6; Shan, Rui2,3,4,5; Yuan, Haoran1,2,3,4,5 ; Chen, Yong1,2,3,4,5
|
| 刊名 | BIOMASS CONVERSION AND BIOREFINERY
 |
| 出版日期 | 2022-07-04 |
| 页码 | 12 |
| ISSN号 | 2190-6815 |
| 关键词 | Electroplating sludge Magnetic catalysts Furfural Selective hydrogenation |
| DOI | 10.1007/s13399-022-02970-8 |
| 通讯作者 | Yuan, Haoran(yuanhr@ms.giec.ac.cn) |
| 英文摘要 | A series of inexpensive electroplating sludge-derived magnetic copper-containing catalysts were developed for the selective hydrogenation of biomass-based furfural (FFR) into furfuryl alcohol (FA) and 2-methylfuran (MF). The specific structural characteristics of as-prepared magnetic copper-containing samples were clearly identified through various techniques, including XRD, XPS, N-2 adsorption-desorption, NH3-TPD, SEM and so on. The characterizations revealed that the hydrogen pre-activated magnetic catalysts supplied metallic Cu species, medium acidity and porosity for the catalytic upgrading of FFR in hydrogen atmosphere. As for FFR-to-FA as well as FFR-to-MF transformations, the magnetic copper-containing catalyst with calcination temperature of 800 degrees C exhibited excellent performance towards the formation of FA and MF, wherein desirable FA yield of 98.5 mol% and MF yield of 71.3 mol% were achieved at reaction temperatures of 160 degrees C and 240 degrees C, respectively. The reuse experiments indicated that the recycled catalysts still maintained excellent activity and stability even after four-time recycling. The present study thus highlights a new approach for the resource utilization of electroplating sludge, which also supplies low-cost and efficient catalytic materials for the selective upgrading of various biomass-derived platform molecules. |
| WOS关键词 | CONVERSION ; ALCOHOL ; CYCLOPENTANONE ; 2-METHYLFURAN ; ACID |
| 资助项目 | National Natural Science Foundation of China[51976222] ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou)[GML2019ZD0101] ; State Key Laboratory of Clean Energy Utilization[ZJUCEU2020023] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| 出版者 | SPRINGER HEIDELBERG |
| WOS记录号 | WOS:000820121200002 |
| 资助机构 | National Natural Science Foundation of China ; Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) ; State Key Laboratory of Clean Energy Utilization |
| 源URL | [http://ir.giec.ac.cn/handle/344007/36937]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yuan, Haoran |
| 作者单位 | 1.South China Agr Univ, Inst Biomass Engn, Guangzhou 510642, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.Southern Marine Sci & Engn Guangdong Lab Guangzho, Guangzhou 511458, Peoples R China 4.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 5.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 6.Zhejiang Univ, State Key Lab Clean Energy Utilizat, Hangzhou 310027, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiao, Yaoxin,Zhang, Jun,Zhu, Lingjun,et al. Electroplating sludge-derived magnetic copper-containing catalysts for selective hydrogenation of bio-based furfural[J]. BIOMASS CONVERSION AND BIOREFINERY,2022:12. |
| APA | Xiao, Yaoxin,Zhang, Jun,Zhu, Lingjun,Shan, Rui,Yuan, Haoran,&Chen, Yong.(2022).Electroplating sludge-derived magnetic copper-containing catalysts for selective hydrogenation of bio-based furfural.BIOMASS CONVERSION AND BIOREFINERY,12. |
| MLA | Xiao, Yaoxin,et al."Electroplating sludge-derived magnetic copper-containing catalysts for selective hydrogenation of bio-based furfural".BIOMASS CONVERSION AND BIOREFINERY (2022):12. |
入库方式： OAI收割
来源：广州能源研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。