Promotion effect of the S-1 zeolite microenvironment on confined Pd nanoparticles for the selective hydrogenation of nitrile
文献类型：期刊论文
| 作者 | Lu, Qiqi1,2; Wei, Xiu-Zhi4; Liu, Jianguo3; Ma, Longlong3
|
| 刊名 | MICROPOROUS AND MESOPOROUS MATERIALS
 |
| 出版日期 | 2022-08-01 |
| 卷号 | 341页码:9 |
| 关键词 | Zeolite microenvironment Pd nanoparticles Encapsulation Nitrile Selective hydrogenation |
| ISSN号 | 1387-1811 |
| DOI | 10.1016/j.micromeso.2022.112086 |
| 通讯作者 | Liu, Jianguo(liujg@seu.edu.cn) ; Ma, Longlong(mall@seu.edu.cn) |
| 英文摘要 | Zeolite-tailored encapsulation of metal nanoparticles exhibits prominent catalytic performance in many fields especially for selective hydrogenation reaction due to the modulation effect of the zeolite microenvironment. Here, Pd nanoparticles encapsulated in MFI zeolite by an in-situ encapsulation method were first used in the selective hydrogenation of nitrile into a primary amine. After introducing KOH for mediating the acid-base property of zeolite microenvironment, the as-synthesized Pd@S-1-K manifested an improved selectivity in the synthesis of primary amine from nitrile, while outperformed both commercial catalysts and conventional Pd supported on zeolite catalyst. The remarkable performance of Pd@S-1-K could be attributed to both the basic property of the S-1-K zeolite for inhibiting the side reactions and the highly dispersed and ultrasmall Pd clusters for superior catalytic activity. Besides, the best yield of 81% was achieved at 80 degrees C, 5 bar H-2, 2 h in ammonia solution via optimization experiments, and the moderate applicability of Pd@S-1-K catalyst was obtained by substrate scope test. |
| WOS关键词 | CLUSTERS ; ENCAPSULATION ; BENZONITRILE ; CATALYSTS ; STABILIZATION ; PERFORMANCE ; PLATINUM ; WATER |
| 资助项目 | National Key R & D Pro- gram of China[2018YFB1501500] ; National Natural Science Founda- tion of China[51976225] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000830046100002 |
| 出版者 | ELSEVIER |
| 资助机构 | National Key R & D Pro- gram of China ; National Natural Science Founda- tion of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/36995]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Liu, Jianguo; Ma, Longlong |
| 作者单位 | 1.Chinese Acad Sci, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China 4.Univ Sci & Technol China, Dept Engn Sci, Hefei 230026, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, Qiqi,Wei, Xiu-Zhi,Liu, Jianguo,et al. Promotion effect of the S-1 zeolite microenvironment on confined Pd nanoparticles for the selective hydrogenation of nitrile[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2022,341:9. |
| APA | Lu, Qiqi,Wei, Xiu-Zhi,Liu, Jianguo,&Ma, Longlong.(2022).Promotion effect of the S-1 zeolite microenvironment on confined Pd nanoparticles for the selective hydrogenation of nitrile.MICROPOROUS AND MESOPOROUS MATERIALS,341,9. |
| MLA | Lu, Qiqi,et al."Promotion effect of the S-1 zeolite microenvironment on confined Pd nanoparticles for the selective hydrogenation of nitrile".MICROPOROUS AND MESOPOROUS MATERIALS 341(2022):9. |
入库方式： OAI收割
来源：广州能源研究所
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