Enhanced chemical looping gasification of biomass coupled with CO2 splitting based on carbon negative emission
文献类型：期刊论文
| 作者 | Wei, Guoqiang1,4; Deng, Lifang1; Yuan, Haoran1,2 ; Yang, Xixian1; Huang, Zhen2; Zheng, Anqing2; Xu, Li3
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| 刊名 | ENERGY CONVERSION AND MANAGEMENT
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| 出版日期 | 2022-05-15 |
| 卷号 | 260页码:11 |
| 关键词 | Biomass CO2 splitting CLGCS Oxygen carrier Carbon negative emission Heterologous metal |
| ISSN号 | 0196-8904 |
| DOI | 10.1016/j.enconman.2022.115597 |
| 通讯作者 | Yuan, Haoran(yuanhaoran81@gmail.com) |
| 英文摘要 | Under the background of fossil fuel consumption and global climate change, an enhanced chemical looping gasification of biomass coupled with CO2 splitting (CLGCS) was proposed in this work to produce high-quality syngas from biomass and split CO2 into CO by using Fe-based mixed oxygen carriers (OCs) without extra catalyst and excessive energy consumption, which provided a carbon negative emission technology for the cascade conversion of biomass and resource utilization of greenhouse gas. The reaction equilibrium and regulation mechanism of CLGCS were analyzed in Ellingham diagrams via theoretical calculation. Variable conditions were designed and performed to investigate the reaction performance of OCs. The intermetallic synergy was analyzed, and the improvement order of heterologous metal on lattice oxygen transfer of OCs was Co2O3 > NiO > CeO2 > CaO. The NiO modified sample exhibited excellent reaction behavior in CLGCS, which provided active sites for catalytic cracking of tar in CLG stage and activating CO2 molecules in splitting stage. Syngas with heating value 13.32 MJ/m(3) and carbon conversion 74.18% were achieved in CLG stage, corresponding to CO2 conversion 64.09% and CO yield 23.59 mmol/g in splitting stage. High temperature enhanced the endothermic reactions in CLGCS process, and the biomass occurrence ratio indicated a positive correlation with CO2 splitting. Although some OC particles agglomerated in reaction process, the pore structure and reactivity remained stable. After 20 cyclic reaction tests, the carbon conversion in CLG stage and CO2 conversion in splitting stage were kept at 67.52% and 73.5%, respectively. The reaction path of CLGCS with NiO modified OC was summarized as: Fe2O3/NiFe2O4 -> Fe/FeO/Ni -> Fe3O4/Ni. Fe2O3/NiFe2O4. |
| WOS关键词 | OXYGEN CARRIERS ; PERFORMANCE ; COMBUSTION ; HYDROGEN ; SYNGAS ; FE ; NI ; TECHNOLOGY ; EVOLUTION ; ILMENITE |
| 资助项目 | National Natural Science Foundation of China[51976226] ; National Natural Science Foundation of China[U1810125] ; National Natural Science Foundation of China[51776133] ; Joint Fund of the Yulin Uni-versity ; Dalian National Laboratory for Clean Energy[2021021] ; Foundation of State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering[2020-KF-04] |
| WOS研究方向 | Thermodynamics ; Energy & Fuels ; Mechanics |
| 语种 | 英语 |
| WOS记录号 | WOS:000830157300004 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 资助机构 | National Natural Science Foundation of China ; Joint Fund of the Yulin Uni-versity ; Dalian National Laboratory for Clean Energy ; Foundation of State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering |
| 源URL | [http://ir.giec.ac.cn/handle/344007/37051]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yuan, Haoran |
| 作者单位 | 1.South China Agr Univ, Inst Biomass Engn, Key Lab Energy Plants Resource & Utilizat, Minist Agr & Rural Affairs, Guangzhou 510642, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.Beijing Univ Technol, Fac Mat & Mfg, Inst Circular Econ, Beijing 100124, Peoples R China 4.Ningxia Univ, Sch Chem & Chem Engn, State Key Lab High Efficiency Utilizat Coal & Gre, Yinchuan 750021, Ningxia, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wei, Guoqiang,Deng, Lifang,Yuan, Haoran,et al. Enhanced chemical looping gasification of biomass coupled with CO2 splitting based on carbon negative emission[J]. ENERGY CONVERSION AND MANAGEMENT,2022,260:11. |
| APA | Wei, Guoqiang.,Deng, Lifang.,Yuan, Haoran.,Yang, Xixian.,Huang, Zhen.,...&Xu, Li.(2022).Enhanced chemical looping gasification of biomass coupled with CO2 splitting based on carbon negative emission.ENERGY CONVERSION AND MANAGEMENT,260,11. |
| MLA | Wei, Guoqiang,et al."Enhanced chemical looping gasification of biomass coupled with CO2 splitting based on carbon negative emission".ENERGY CONVERSION AND MANAGEMENT 260(2022):11. |
入库方式： OAI收割
来源：广州能源研究所
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