Photoelectrochemical effect of Cu 2 O on the corrosion behavior of Cu in sodium sulfate solution
文献类型:期刊论文
作者 | Li, Jiarun3; Qian, Feng3; Guo, Chongqing3; Wang, Ning2; Chen, Zhuoyuan1; Wang, Lei3 |
刊名 | JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY |
出版日期 | 2023-10-10 |
卷号 | 160页码:46-54 |
ISSN号 | 1005-0302 |
关键词 | Photoinduced corrosion Copper SVET P -type semiconductor |
DOI | 10.1016/j.jmst.2023.03.020 |
通讯作者 | Wang, Ning(wangning@qdio.ac.cn) ; Chen, Zhuoyuan(zychen@fosu.edu.cn) |
英文摘要 | The electrochemical associated with photoelectrochemical behaviors of Cu electrodeposited with Cu 2 O layer were investigated in this work. The corrosion of Cu was promoted due to the enhanced anodic and cathodic processes under AM 1.5illumination compared with that in the darkness, especially for the anodic process. The photoinduced corrosion of Cu by Cu 2 O was detected by Scanning Vibrating Electro Technique (SVET). The effect of Cu 2 O on the promotion of Cu corrosion under illumination can be ascribed to the narrowed depletion layer in Cu 2 O under illumination, which facilitates the separation of hole-electron pairs. The resultant holes give rise to the oxidation of the Cu matrix and lead to a promoted corrosion consequently. Besides, a method for in-situ determining the photoinduced current of a semiconductor material is proposed. (c) 2023 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology. |
WOS关键词 | ATMOSPHERIC CORROSION ; VISIBLE-LIGHT ; PHOTO-CORROSION ; COPPER ; FILM ; PHOTOCATHODES ; DEPOSITION ; MECHANISM ; EFFICIENT ; OZONE |
资助项目 | Natural Science Foundation of Shandong[ZR2021MD002] ; National Natural Science Foundation of China[41576114] ; National Natural Science Foundation of China[42106051] ; National Natural Science Foundation of China[U2106206] |
WOS研究方向 | Materials Science ; Metallurgy & Metallurgical Engineering |
语种 | 英语 |
出版者 | JOURNAL MATER SCI TECHNOL |
WOS记录号 | WOS:000990838900001 |
源URL | [http://ir.qdio.ac.cn/handle/337002/183110] |
专题 | 海洋研究所_海洋腐蚀与防护研究发展中心 |
通讯作者 | Wang, Ning; Chen, Zhuoyuan |
作者单位 | 1.Foshan Univ, Sch Mat Sci & Hydrogen Energy, Foshan 528000, Peoples R China 2.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China 3.Qingdao Univ Sci & Technol, Sch Environm & Safety Engn, Qingdao 266042, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Jiarun,Qian, Feng,Guo, Chongqing,et al. Photoelectrochemical effect of Cu 2 O on the corrosion behavior of Cu in sodium sulfate solution[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2023,160:46-54. |
APA | Li, Jiarun,Qian, Feng,Guo, Chongqing,Wang, Ning,Chen, Zhuoyuan,&Wang, Lei.(2023).Photoelectrochemical effect of Cu 2 O on the corrosion behavior of Cu in sodium sulfate solution.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,160,46-54. |
MLA | Li, Jiarun,et al."Photoelectrochemical effect of Cu 2 O on the corrosion behavior of Cu in sodium sulfate solution".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 160(2023):46-54. |
入库方式: OAI收割
来源:海洋研究所
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