Multiple PAHs' Detection under CDOM Interference Based on Excitation-Emission Matrix and Interval Selection
文献类型:期刊论文
作者 | Li, Ruizhuo2,3; Gao, Limin2,3; Wu, Guojun1,3; Dong, Jing2,3 |
刊名 | JOURNAL OF SPECTROSCOPY |
出版日期 | 2023-12 |
卷号 | 2023 |
ISSN号 | 2314-4920;2314-4939 |
DOI | 10.1155/2023/7105348 |
产权排序 | 1 |
英文摘要 | Fluorescence technology is an effective tool for detecting polycyclic aromatic hydrocarbons (PAHs) in water. However, the accuracy of fluorescence detection is reduced by the spectral overlap of different PAHs and coexisting colored dissolved organic matter (CDOM). In this study, a single-excitation interval selection method based on an excitation-emission matrix is proposed to quantify four PAHs: fluorene, pyrene, phenanthrene, and benzo(a)pyrene under CDOM interference. The optimal excitation wavelength for each PAH was obtained by stability analysis, based on which the optimal emission interval was obtained by chaotic particle swarm optimization. The partial least squares (PLS) prediction models of four PAHs under interference were established. On comparing with other modeling methods, the results show that the models with interval selection have better prediction accuracy (mean relative error < 10%) under CDOM interference. The recovery rate and limit of detection of the method were also evaluated. This study provides a new and helpful strategy for fluorescence detection of interfering PAHs in water. |
语种 | 英语 |
出版者 | HINDAWI LTD |
WOS记录号 | WOS:001129714800001 |
源URL | [http://ir.opt.ac.cn/handle/181661/97095] |
专题 | 海洋光学技术研究室 |
通讯作者 | Wu, Guojun |
作者单位 | 1.Qingdao Marine Sci & Technol Ctr, Qingdao 266237, Shandong, Peoples R China 2.Univ Chinese Acad Sci, Coll Photoelect, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Xian Inst Opt & Precis Mech, Xian 710119, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Ruizhuo,Gao, Limin,Wu, Guojun,et al. Multiple PAHs' Detection under CDOM Interference Based on Excitation-Emission Matrix and Interval Selection[J]. JOURNAL OF SPECTROSCOPY,2023,2023. |
APA | Li, Ruizhuo,Gao, Limin,Wu, Guojun,&Dong, Jing.(2023).Multiple PAHs' Detection under CDOM Interference Based on Excitation-Emission Matrix and Interval Selection.JOURNAL OF SPECTROSCOPY,2023. |
MLA | Li, Ruizhuo,et al."Multiple PAHs' Detection under CDOM Interference Based on Excitation-Emission Matrix and Interval Selection".JOURNAL OF SPECTROSCOPY 2023(2023). |
入库方式: OAI收割
来源:西安光学精密机械研究所
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