中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effects of exogenous phosphates on speciation and bioavailability of arsenic and cadmium in farmland soils

文献类型:期刊论文

作者Zhang, Meng; Wang, Xuemei; Wei, Chaoyang2; Wang, Menglu; Han, Wei; Yuan, Zhuang; Ji, Hongbing
刊名JOURNAL OF SOILS AND SEDIMENTS
出版日期2023-04-01
卷号N/A
关键词Soil pH Available P Stability Bioavailability Synchrotron radiation
DOI10.1007/s11368-023-03448-4
文献子类Article ; Early Access
英文摘要Purpose Soils contaminated with As and Cd complex pose a serious threat to human health and the ecological environment. Phosphorus is an essential nutrient element in farmland soil, and it is of great significance to study the effects of different types of phosphate on the compound pollution of As and Cd in soil.Methods Four types of phosphates, including aluminum phosphate (AlPO4), ferric phosphate (FePO4), calcium phosphate (Ca-3(PO4)(2)), and potassium dihydrogen phosphate (KH2PO4), were selected to explore the effect of different phosphates on the stability and bioavailability of soil As and Cd by changing soil pH and the concentration of available P. X-ray absorption near edge structure (XANES) spectroscopy was used to determine P speciation in soil samples.Results The results show that all four phosphates can improve the stability of Cd in soil, but the concentration of unstable As in soil increased after applying P because of the competitive effect. Potassium dihydrogen phosphate and ferric phosphate remarkably affected As and Cd. At pH 6.75, both As and Cd in soil can reach a relatively stable state. With the increase in available P in soil, the bioavailability of Cd decreased linearly, while that of As increased exponentially. The fitting curve shows that the available P content of 450 mg/kg can be used as the critical point to control the relative stability of As and Cd in the sampled soil.Conclusion Phosphate can alter the stability of As and Cd by changing soil pH and available P content.
WOS关键词HEAVY-METALS ; WATER MANAGEMENT ; PHOSPHORUS ; AVAILABILITY ; ACCUMULATION ; PH ; ADSORPTION ; PHYTOAVAILABILITY ; IMMOBILIZATION ; CONTAMINATION
WOS研究方向Environmental Sciences & Ecology ; Agriculture
WOS记录号WOS:000926428700001
源URL[http://ir.igsnrr.ac.cn/handle/311030/200757]  
专题陆地表层格局与模拟院重点实验室_外文论文
作者单位1.Chinese Acad Sci, Inst Geog Sci & Nat Resources Res, Key Lab Land Surface Pattern & Simulat, Beijing, Peoples R China
2.Univ Sci & Technol Beijing, Sch Energy & Environm Engn, Beijing Key Lab Resource Oriented Treatment Ind Po, Int Sci & Technol Cooperat Base Environm & Energy, Xueyuan Rd 30, Beijing 100083, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Meng,Wang, Xuemei,Wei, Chaoyang,et al. Effects of exogenous phosphates on speciation and bioavailability of arsenic and cadmium in farmland soils[J]. JOURNAL OF SOILS AND SEDIMENTS,2023,N/A.
APA Zhang, Meng.,Wang, Xuemei.,Wei, Chaoyang.,Wang, Menglu.,Han, Wei.,...&Ji, Hongbing.(2023).Effects of exogenous phosphates on speciation and bioavailability of arsenic and cadmium in farmland soils.JOURNAL OF SOILS AND SEDIMENTS,N/A.
MLA Zhang, Meng,et al."Effects of exogenous phosphates on speciation and bioavailability of arsenic and cadmium in farmland soils".JOURNAL OF SOILS AND SEDIMENTS N/A(2023).

入库方式: OAI收割

来源:地理科学与资源研究所

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