A Quantity Chalcopyrite Reference Material for In Situ Sulfur Isotope Analysis
文献类型：期刊论文
| 作者 | Chen, Youwei1; Chen, Liemeng1; Tang, Guoqiang5; Bao, Zhian4; Cui, Zexian3; Qiu, Xincheng2; Chen, Zhong-Qiang2; Gu, Jing1; Dong, Shaohua1; Gao, Jianfeng1 |
| 刊名 | ATOMIC SPECTROSCOPY
 |
| 出版日期 | 2023-05-01 |
| 卷号 | 44期号:3页码:131-141 |
| ISSN号 | 0195-5373 |
| DOI | 10.46770/AS.2023.141 |
| 英文摘要 | Secondary ion mass spectrometry (SIMS) for sulfur isotope analysis in chalcopyrite is an essential technique with exceptional spatial resolution, which enables precise constraints on mineralization mechanisms. However, the scarcity of matrix-matched chalcopyrite reference materials (RM) for SIMS hinders its accuracy and reliability. This study introduces a large-grained natural chalcopyrite RM (IGSD) for precise sulfur isotope analysis (delta S-34) using SIMS and laser ablation multicollector-inductively coupled plasma mass spectrometry (LA-MC-ICPMS). Petrographic examination and electron microprobe analysis (EMPA) results confirm the homogeneity of major elements in the IGSD chalcopyrite grains. The results of in situ analysis at four SIMS laboratories and one LA-MC-ICPMS laboratory and bulk analysis confirm the homogeneity of the S isotope composition in the IGSD chalcopyrite grains. The in situ analysis result is consistent with the result of isotope ratio mass spectroscopy (IRMS), which falls within the same range of uncertainty. This supports the suitability of the IGSD chalcopyrite RM for in situ S isotope analysis. The recommended delta S-34 value of the IGSD chalcopyrite RM, based on IRMS, is 4.21 +/- 0.23% (2SD, n = 30). |
| WOS关键词 | MASS-SPECTROMETRY ; ICP-MS ; SULFIDE ; COPPER ; SIMS ; DEPOSITS ; SULFATE ; MICROPROBE ; RESOLUTION ; MINERALS |
| 资助项目 | National Key Research and Development Program of China[2018YFA0702602] ; National Natural Science Foundation of China[42025301] |
| WOS研究方向 | Spectroscopy |
| 语种 | 英语 |
| WOS记录号 | WOS:001047694500003 |
| 出版者 | ATOMIC SPECTROSCOPY PRESS LTD |
| 资助机构 | National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China |
| 源URL | [http://ir.iggcas.ac.cn/handle/132A11/111442]  |
| 专题 | 地质与地球物理研究所_中国科学院地球与行星物理重点实验室 |
| 通讯作者 | Chen, Youwei; Gao, Jianfeng |
| 作者单位 | 1.Chinese Acad Sci, Inst Geochem, State Key Lab Ore Deposit Geochem, Guiyang 550081, Peoples R China 2.China Univ Geosci, State Key Lab Biogeol & Environm Geol, Wuhan 430074, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Geochem, State Key Lab Isotope Geochem, Guangzhou 510604, Peoples R China 4.Northwest Univ, Dept Geol, State Key Lab Continental Dynam, Xian 710069, Peoples R China 5.Chinese Acad Sci, Inst Geol & Geophys, State Key Lab Earth & Planetary Phys, Beijing 100029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Youwei,Chen, Liemeng,Tang, Guoqiang,et al. A Quantity Chalcopyrite Reference Material for In Situ Sulfur Isotope Analysis[J]. ATOMIC SPECTROSCOPY,2023,44(3):131-141. |
| APA | Chen, Youwei.,Chen, Liemeng.,Tang, Guoqiang.,Bao, Zhian.,Cui, Zexian.,...&Gao, Jianfeng.(2023).A Quantity Chalcopyrite Reference Material for In Situ Sulfur Isotope Analysis.ATOMIC SPECTROSCOPY,44(3),131-141. |
| MLA | Chen, Youwei,et al."A Quantity Chalcopyrite Reference Material for In Situ Sulfur Isotope Analysis".ATOMIC SPECTROSCOPY 44.3(2023):131-141. |
入库方式： OAI收割
来源：地质与地球物理研究所
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