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Sterically demanding Csp2(ortho-substitution)-Csp3(tertiary) bond formation via carboxylate-directed Mizoroki-Heck reaction under extra-ligand-free conditions

文献类型：期刊论文

作者Zeng, Wei2,3; Chen, Ai-Wen2,3; Yan, Ming-Jie2,3; Wang, Jie1,2,3
刊名ORGANIC & BIOMOLECULAR CHEMISTRY
出版日期2023-11-22
页码5
ISSN号1477-0520
DOI10.1039/d3ob01784b
通讯作者Wang, Jie(jiewang@simm.ac.cn)
英文摘要Construction of the sterically demanding Csp(2()oS)-Csp(3)(T) bond was achieved by carrying out the Pd-catalyzed carboxylate-directed Mizoroki-Heck reaction under extra-ligand-free aqueous conditions. The cooperative role of the presence of water with the absence of phosphine ligand was proposed to accelerate the migratory insertion process considerably, delivering a broad substrate scope.
WOS关键词CROSS-COUPLING REACTIONS ; MECHANISM ; ARYLATION ; CENTERS ; HALIDES ; WATER
资助项目National Outstanding Youth Science Fund Project of National Natural Science Foundation of China[22101290] ; National Natural Science Foundation of China ; Chinese Academy of Sciences and Shanghai Institute of Materia Medica
WOS研究方向Chemistry
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:001113902000001
源URL[http://119.78.100.183/handle/2S10ELR8/308134]  
专题中国科学院上海药物研究所
通讯作者Wang, Jie
作者单位1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Chem Biol, Shanghai 201203, Peoples R China
3.Nanjing Univ Chinese Med, Sch Chinese Mat Med, Nanjing 210023, Peoples R China
推荐引用方式
GB/T 7714		 Zeng, Wei,Chen, Ai-Wen,Yan, Ming-Jie,et al. Sterically demanding Csp2(ortho-substitution)-Csp3(tertiary) bond formation via carboxylate-directed Mizoroki-Heck reaction under extra-ligand-free conditions[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2023:5.
APA Zeng, Wei,Chen, Ai-Wen,Yan, Ming-Jie,&Wang, Jie.(2023).Sterically demanding Csp2(ortho-substitution)-Csp3(tertiary) bond formation via carboxylate-directed Mizoroki-Heck reaction under extra-ligand-free conditions.ORGANIC & BIOMOLECULAR CHEMISTRY,5.
MLA Zeng, Wei,et al."Sterically demanding Csp2(ortho-substitution)-Csp3(tertiary) bond formation via carboxylate-directed Mizoroki-Heck reaction under extra-ligand-free conditions".ORGANIC & BIOMOLECULAR CHEMISTRY (2023):5.

入库方式： OAI收割

来源：上海药物研究所

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