(B, N)-Rich B-C-N Nanosheet-assembled Microwires as Effective Electrocatalysts for Oxygen Reduction Reaction
文献类型：期刊论文
| 作者 | Cao, Lihua1; Yang, Tao2; Mo, Haixin1; Zhang, Yafang1; Gao, Yongmin1; Xu, Zhiyong3; Kang, Bing1; Xia, Xuefeng1; Zhang, Wenhua1; Xu, Zhihao1 |
| 刊名 | CHEMNANOMAT
 |
| 出版日期 | 2023-12-13 |
| 页码 | 7 |
| ISSN号 | 2199-692X |
| 关键词 | oxygen reduction reaction electrocatalyst carbon B-C-N |
| DOI | 10.1002/cnma.202300487 |
| 通讯作者 | Cao, Lihua(2022994820@nit.edu.cn) ; Hou, Xue(houx@idsse.ac.cn) |
| 英文摘要 | Developing highly active and stable nanocarbon electrocatalysts for the oxygen reduction reaction (ORR) in alkaline medium has attracted much attention due to their potential as an alternative to traditional metal-based or noble metal catalysts. Herein, a unique micro-nano structure of (B, N)-rich B-C-N nanosheet-assembled microwires (BCNNAM) were synthesized and driven electrochemical oxide reduction reaction. The diameter of the microwires about 1 mu m, while the nanosheets have an average thickness of less than 20 nm. The compact nanosheets are mostly separated with a bending, curling and crumpling morphology. All those constitutes a ternary system with large surface area and abundant activity sites facilitate fast mass/electron transport for ORR catalytic activity. Thus, the B, N-rich B-C-N nanosheet-assembled microwires show significantly improved electrocatalytic activity with an onset potential of 0.95 V and half-wave potential of 0.83 V compared to BNNAM, nitride-doped carbon, porous carbon and a commercial Pt/C electrocatalyst. Such high catalytic performance of B, N-rich B-C-N micro-nano structures is due to the enhanced activity by the coexistence of B, C and N and the mass transfer promoted by the unique hierarchical porous structure. B, N-rich BCNNAM (nanosheet-assembled microwires), produced via a conbining growth mechanism of VLS and VS, showed excellent electrocatalytic performances for ORR due to synergistic effect arising from B, C and N as well as hierarchical porous structure.image |
| WOS关键词 | HEXAGONAL BORON-NITRIDE ; METAL-FREE CATALYST ; CARBON NANOTUBES ; SURFACE-DEFECTS ; GRAPHENE OXIDE ; ACTIVE-SITES ; NITROGEN ; PERFORMANCE ; GROWTH ; NANOCARBON |
| 资助项目 | Foundation of Jiangxi Educational Commission[GJJ2201519] ; Foundation of Jiangxi Educational Committee[20224BAB216101] ; Natural Science Foundation of Jiangxi Province of China |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:001124881400001 |
| 资助机构 | Foundation of Jiangxi Educational Commission ; Foundation of Jiangxi Educational Committee ; Natural Science Foundation of Jiangxi Province of China |
| 源URL | [http://ir.idsse.ac.cn/handle/183446/10738]  |
| 专题 | 深海科学研究部_深海极端环境模拟研究实验室 |
| 通讯作者 | Cao, Lihua; Hou, Xue |
| 作者单位 | 1.Nanchang Inst Technol, Sch Elect Engn, 289 Tianxiang Rd, Nanchang 330099, Jiangxi, Peoples R China 2.Hainan Univ, Sch Mat Sci & Engn, Special Glass Key Lab Hainan Prov, 58 Renmin Ave, Haikou 570228, Hainan, Peoples R China 3.Jiangxi Acad Sci, Inst Appl Chem, 7777 Changdong Ave, Nanchang 330096, Jiangxi, Peoples R China 4.Chinese Acad Sci, Inst Deep Sea Sci & Engn, CAS Key Lab Expt Study Deep Sea Extreme Condit, 16 Luhuitou Rd, Sanya 572000, Hainan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cao, Lihua,Yang, Tao,Mo, Haixin,et al. (B, N)-Rich B-C-N Nanosheet-assembled Microwires as Effective Electrocatalysts for Oxygen Reduction Reaction[J]. CHEMNANOMAT,2023:7. |
| APA | Cao, Lihua.,Yang, Tao.,Mo, Haixin.,Zhang, Yafang.,Gao, Yongmin.,...&Hou, Xue.(2023).(B, N)-Rich B-C-N Nanosheet-assembled Microwires as Effective Electrocatalysts for Oxygen Reduction Reaction.CHEMNANOMAT,7. |
| MLA | Cao, Lihua,et al."(B, N)-Rich B-C-N Nanosheet-assembled Microwires as Effective Electrocatalysts for Oxygen Reduction Reaction".CHEMNANOMAT (2023):7. |
入库方式： OAI收割
来源：深海科学与工程研究所
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