Litosetoenins A-E, Diterpenoids from the Soft Coral Litophyton setoensis, Backbone-Rearranged through Divergent Cyclization Achieved by Epoxide Reactivity Inversion
文献类型：期刊论文
| 作者 | Li, Song-Wei1; Mudianta, I. Wayan2; Cuadrado, Cristina3; Li, Geng1; Yudasmara, Gede A.4; Setiabudi, Gede, I4; Daranas, Antonio H.3; Guo, Yue-Wei1
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| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
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| 出版日期 | 2021-09-03 |
| 卷号 | 86期号:17页码:11771-11781 |
| ISSN号 | 0022-3263 |
| DOI | 10.1021/acs.joc.1c01218 |
| 文献子类 | Article |
| 英文摘要 | Litosetoenins A-E (1-5), five new ring-rearranged serrulatane-type diterpenoids with a common tricyclo[3.0.4]-decane core, along with a known diterpenoid glycoside (6), a related known diterpenoid (7), and four known sesquiterpenoids (8-11), were isolated from a Balinese soft coral Litophyton setoensis. Spirolitosetoenin A (5a) and isospirolitosetoenin A (5b), featuring an unprecedented spiro[4,5]decane core, were obtained after treatment of compound 5 with HCl in methanol. The structures of new compounds were elucidated by extensive spectroscopic analysis, quantum mechanical nuclear magnetic resonance approach, and chemical methods. A plausible bio-ynthetic pathway involving an unusual divergent biogenesis was proposed. |
| WOS关键词 | SESQUITERPENOIDS ; STEREOCHEMISTRY ; TERPENOIDS ; SYNTHASE ; STEROIDS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000693628600041 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/309373]  |
| 专题 | 新药研究国家重点实验室 |
| 通讯作者 | Daranas, Antonio H.; Guo, Yue-Wei |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, Shanghai 201203, Peoples R China; 2.Univ Pendidikan Ganesha, Dept Chem, Bali 81116, Indonesia; 3.Consejo Super Invest Cient IPNA CSIC, Inst Prod Nat & Agrobiol, Tenerife 38206, Spain; 4.Univ Pendidikan Ganesha, Study Program Aquaculture, Bali 81116, Indonesia |
| 推荐引用方式 GB/T 7714 | Li, Song-Wei,Mudianta, I. Wayan,Cuadrado, Cristina,et al. Litosetoenins A-E, Diterpenoids from the Soft Coral Litophyton setoensis, Backbone-Rearranged through Divergent Cyclization Achieved by Epoxide Reactivity Inversion[J]. JOURNAL OF ORGANIC CHEMISTRY,2021,86(17):11771-11781. |
| APA | Li, Song-Wei.,Mudianta, I. Wayan.,Cuadrado, Cristina.,Li, Geng.,Yudasmara, Gede A..,...&Guo, Yue-Wei.(2021).Litosetoenins A-E, Diterpenoids from the Soft Coral Litophyton setoensis, Backbone-Rearranged through Divergent Cyclization Achieved by Epoxide Reactivity Inversion.JOURNAL OF ORGANIC CHEMISTRY,86(17),11771-11781. |
| MLA | Li, Song-Wei,et al."Litosetoenins A-E, Diterpenoids from the Soft Coral Litophyton setoensis, Backbone-Rearranged through Divergent Cyclization Achieved by Epoxide Reactivity Inversion".JOURNAL OF ORGANIC CHEMISTRY 86.17(2021):11771-11781. |
入库方式： OAI收割
来源：上海药物研究所
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