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Uncommon Polycyclic Merosesquiterpenoids and Asteriscanoids from the Hainan Soft Coral Sinularia humesi†

文献类型：期刊论文

作者Chen, Zi-Hui1,2; Yao, Li-Gong1; Wu, Qihao1; Guo, Yue-Wei1,2
刊名CHINESE JOURNAL OF CHEMISTRY
出版日期2021-05-11
卷号39期号:9页码:2377-2385
ISSN号1001-604X
关键词Soft coral Sinularia humesi Terpenoids X-ray diffraction Configuration determination
DOI10.1002/cjoc.202100236
文献子类Article
英文摘要Main observation and conclusion A rare highly fused racemic merosesquiterpenoid, 9-epi-verrubenzospirolactone (1), six new asteriscane-type sesquiterpenoids, sinuhumesins A-F (4-9), and two related known ones (10 and 11) were isolated from Hainan soft coral Sinularia humesi. Compound 1 was further separated by chiral HPLC resolution to one pair of enantiomers [(+)-1 and (-)-1], respectively. The full structures of the new compounds were unambiguously determined by extensive spectroscopic analysis, chemical computation approaches, modified Mosher's method and/or X-ray diffraction analysis, as well as comparison with previously reported data of related model compounds.
WOS关键词ABSOLUTE-CONFIGURATION ; CEMBRANOIDS ; SESQUITERPENOIDS
WOS研究方向Chemistry
语种英语
出版者WILEY-V C H VERLAG GMBH
WOS记录号WOS:000668843200001
源URL[http://119.78.100.183/handle/2S10ELR8/309377]  
专题新药研究国家重点实验室
通讯作者Wu, Qihao; Guo, Yue-Wei
作者单位1.Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, 555 Zu Chong Zhi Rd,Zhangjiang Hitech Pk, Shanghai 201203, Peoples R China;
2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714		 Chen, Zi-Hui,Yao, Li-Gong,Wu, Qihao,et al. Uncommon Polycyclic Merosesquiterpenoids and Asteriscanoids from the Hainan Soft Coral Sinularia humesi†[J]. CHINESE JOURNAL OF CHEMISTRY,2021,39(9):2377-2385.
APA Chen, Zi-Hui,Yao, Li-Gong,Wu, Qihao,&Guo, Yue-Wei.(2021).Uncommon Polycyclic Merosesquiterpenoids and Asteriscanoids from the Hainan Soft Coral Sinularia humesi†.CHINESE JOURNAL OF CHEMISTRY,39(9),2377-2385.
MLA Chen, Zi-Hui,et al."Uncommon Polycyclic Merosesquiterpenoids and Asteriscanoids from the Hainan Soft Coral Sinularia humesi†".CHINESE JOURNAL OF CHEMISTRY 39.9(2021):2377-2385.

入库方式： OAI收割

来源：上海药物研究所

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