Efficiently simultaneous sorption and oxidation of antimonite on nitroso grafting-manganese loading binary-modified biochar from aqueous solution
文献类型：期刊论文
| 作者 | Zhang, Liping3,5; Yang, Daizong2,5; Tao, Yanru5; Jiang, Xia5; Wang, Liang4; Wang, Haonan5; Liu, Yaqing5; Meng, Xiaofan5; Niu, Yuan5; Niu, Yong5 |
| 刊名 | SEPARATION AND PURIFICATION TECHNOLOGY
 |
| 出版日期 | 2024-06-13 |
| 卷号 | 337页码:11 |
| ISSN号 | 1383-5866 |
| 关键词 | Antimonite Nitroso Manganese Adsorption Oxidation |
| DOI | 10.1016/j.seppur.2024.126398 |
| 通讯作者 | Luo, Mingke(luo.mingke@craes.org.cn) |
| 英文摘要 | Modification of the biochar platform with organic reagents could enrich active functional groups, and incorporation of magnetic mineral on it could facilitate separation from the aqueous solution after practical application. The present research took advantage of both by performing -NO2 grafting and MnOx loading binary modification on biochar derived from bagasse. The results demonstrated that the binary modification dramatically enhanced the antimonite (Sb(III)) adsorption ability of the sole-modified biochar. The Sb(III) sorption experiment revealed the optimal binary modified parameters were 300 degrees C pyrolysis temperature and the reagent doses of 2.0 g urea, 1.0 g NaOH, 1.5 mL CCl4, 2.0 g NaNO2, and 0.1 g KMnO4. Binary-modified biochar synthesized under the optimal condition (MNBC300) could efficiently remove Sb(III) in the aqueous solution with an adsorption amount of 142.86 mg/g, which was much higher than that of the sole (27.70 and 13.43 mg/g). At a fast rate, the Sb(III) sorption behavior was governed by multilayer heterogeneous chemisorption adsorption via the complexation between-NO2/Mn-O bond and Sb(III). Fitting peaks on X-ray photoelectron spectra (XPS) demonstrated the oxidizability of MNBC300 due to the electron transfer from Sb(III) to Mn3+, which was thereby oxidizing Sb(III) to less toxic Sb(V). Overall, the present study showed a novel biochar modification technique to eliminate the ecological and human health hazards of Sb-containing wastewater. |
| WOS关键词 | REMOVAL ; SB(III) ; ADSORPTION ; SB(V) ; SPECIATION ; OXIDE |
| 资助项目 | Fundamental Research Funds for the Central Public -interest Scientific Institution[2022YSKY- 47] ; National Key Research and Development Program of China[2022YFC3204005] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| 出版者 | ELSEVIER |
| WOS记录号 | WOS:001166355400001 |
| 资助机构 | Fundamental Research Funds for the Central Public -interest Scientific Institution ; National Key Research and Development Program of China |
| 源URL | [http://ir.igsnrr.ac.cn/handle/311030/202942]  |
| 专题 | 中国科学院地理科学与资源研究所 |
| 通讯作者 | Luo, Mingke |
| 作者单位 | 1.Chinese Res Inst Environm Sci, Beijing 100012, Peoples R China 2.Guangxi Minzu Univ, Sch Mat & Environm, Key Lab Environm Friendly Mat & New Technol Carbon, Guangxi Key Lab Adv Struct Mat & Carbon Neutraliza, Nanning, 530105, Peoples R China 3.Tsinghua Univ, Sch Environm, Beijing 100083, Peoples R China 4.Chinese Acad Sci, Inst Geog Sci & Nat Resources Res, Beijing 100101, Peoples R China 5.Chinese Res Inst Environm Sci, State Key Lab Environm Criteria & Risk Assessment, Natl Engn Lab Lake Pollut Control & Ecol Restorat, State Environm Protect Key Lab Lake Pollut Control, Beijing 100012, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Liping,Yang, Daizong,Tao, Yanru,et al. Efficiently simultaneous sorption and oxidation of antimonite on nitroso grafting-manganese loading binary-modified biochar from aqueous solution[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2024,337:11. |
| APA | Zhang, Liping.,Yang, Daizong.,Tao, Yanru.,Jiang, Xia.,Wang, Liang.,...&Luo, Mingke.(2024).Efficiently simultaneous sorption and oxidation of antimonite on nitroso grafting-manganese loading binary-modified biochar from aqueous solution.SEPARATION AND PURIFICATION TECHNOLOGY,337,11. |
| MLA | Zhang, Liping,et al."Efficiently simultaneous sorption and oxidation of antimonite on nitroso grafting-manganese loading binary-modified biochar from aqueous solution".SEPARATION AND PURIFICATION TECHNOLOGY 337(2024):11. |
入库方式： OAI收割
来源：地理科学与资源研究所
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