Procedures from samples to sulfur isotopic data: A review
文献类型：期刊论文
| 作者 | Zhao, Changqiu1,2; Guo, Qingjun2,3,6; Zhang, Tonggang4; Han, Xiaokun5; Usman, Dawuda1,2 |
| 刊名 | RAPID COMMUNICATIONS IN MASS SPECTROMETRY
 |
| 出版日期 | 2024-06-15 |
| 卷号 | 38期号:11页码:27 |
| ISSN号 | 0951-4198 |
| DOI | 10.1002/rcm.9733 |
| 通讯作者 | Guo, Qingjun(guoqj@igsnrr.ac.cn) |
| 英文摘要 | RationaleSulfur isotopes have been widely used to solve some key scientific questions, especially in the last two decades with advanced instruments and analytical schemes. Different sulfur speciation and multiple isotopes analyzed in laboratories worldwide and in situ microanalysis have also been reported in many articles. However, methods of sampling to measurements are multifarious, and occasionally some inaccuracies are present in published papers. Vague methods may mislead newcomers to the field, puzzle readers, or lead to incorrect data-based correlations.MethodsWe have reviewed multiple methods on sulfur isotopic analyses from the perspectives of sampling, laboratory work, and instrumental analysis in order to help reduce operational inhomogeneity and ensure the fidelity of sulfur isotopic data. We do not deem our proposed solutions as the ultimate standard methods but as a lead-in to the overall introduction and summary of the current methods used.ResultsIt has been shown that external contamination and transformation of different sulfur species should be avoided during the sampling, pretreatment, storage, and chemical treatment processes. Conversion rates and sulfur isotopic fractionations during sulfur extraction, purification, and conversion processes must be verified by researchers using standard or known samples. The unification of absence of isotopic fractionation is needed during all steps, and long-term monitoring of standard samples is recommended.ConclusionThis review compiles more details on different methods in sampling, laboratory operation, and measurement of sulfur isotopes, which is beneficial for researchers' better practice in laboratories. Microanalyses and molecular studies are the frontier techniques that compare the bulk sample with the elemental analysis/continuous flow-gas source stable isotope ratio mass spectrometry method, but the latter is widely used. The development of sulfur isotopic measurements will lead to the innovation in scientific issues with sulfur proxies. |
| WOS关键词 | CARBONATE-ASSOCIATED SULFATE ; DRIVEN ANAEROBIC OXIDATION ; REDUCED INORGANIC SULFUR ; RATIO MASS-SPECTROMETRY ; MARINE REDOX CONDITIONS ; HIGH-PRECISION ANALYSIS ; ACID VOLATILE SULFIDE ; MC-ICP-MS ; OXYGEN-ISOTOPE ; ELEMENTAL SULFUR |
| 资助项目 | National Natural Science Foundation of China ; National Key Research & Development Program of China[473] ; National Key Research & Development Program of China[2022YFC3701303] ; Guizhou Bureau of Science and Technology[[2020] 4Y241] ; [U2344228] |
| WOS研究方向 | Biochemistry & Molecular Biology ; Chemistry ; Spectroscopy |
| 语种 | 英语 |
| WOS记录号 | WOS:001198584600001 |
| 出版者 | WILEY |
| 资助机构 | National Natural Science Foundation of China ; National Key Research & Development Program of China ; Guizhou Bureau of Science and Technology |
| 源URL | [http://ir.igsnrr.ac.cn/handle/311030/204776]  |
| 专题 | 中国科学院地理科学与资源研究所 |
| 通讯作者 | Guo, Qingjun |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing, Peoples R China 2.Chinese Acad Sci, Inst Geog Sci & Nat Resources Res, Ctr Environm Remediat, Beijing, Peoples R China 3.Univ Chinese Acad Sci, Coll Resources & Environm, Beijing, Peoples R China 4.China Univ Petr, Coll Geosci, Beijing, Peoples R China 5.Tianjin Univ, Inst Surface Earth Syst Sci, Sch Earth Syst Sci, Tianjin, Peoples R China 6.Chinese Acad Sci, Inst Geog Sci & Nat Resources Res, Ctr Environm Remediat, 11A Datun Rd, Beijing 100101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Changqiu,Guo, Qingjun,Zhang, Tonggang,et al. Procedures from samples to sulfur isotopic data: A review[J]. RAPID COMMUNICATIONS IN MASS SPECTROMETRY,2024,38(11):27. |
| APA | Zhao, Changqiu,Guo, Qingjun,Zhang, Tonggang,Han, Xiaokun,&Usman, Dawuda.(2024).Procedures from samples to sulfur isotopic data: A review.RAPID COMMUNICATIONS IN MASS SPECTROMETRY,38(11),27. |
| MLA | Zhao, Changqiu,et al."Procedures from samples to sulfur isotopic data: A review".RAPID COMMUNICATIONS IN MASS SPECTROMETRY 38.11(2024):27. |
入库方式： OAI收割
来源：地理科学与资源研究所
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