Application insights of environmental catalysts: Synergistic effects of cellulose-based porogens and catalytic metal sites in toluene catalytic oxidation
文献类型：期刊论文
| 作者 | Zhang CH(张晨航)3,4; Liang, Wenjun3; Dou, Baojuan2; Zhu, Yuxue3; Yan, Ningna2; Zhang, Yue1 ; Salleh, Sazlina1; Bin F(宾峰)4
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| 刊名 | FUEL
 |
| 出版日期 | 2024-07-01 |
| 卷号 | 367页码:13 |
| 关键词 | Volatile organic compounds Catalytic oxidation Hierarchical pore structure Bacterial cellulose Environmentally friendly catalysts |
| ISSN号 | 0016-2361 |
| DOI | 10.1016/j.fuel.2024.131402 |
| 通讯作者 | Bin, Feng(binfeng@imech.ac.cn) |
| 英文摘要 | Utilizing environmentally-friendly bacterial cellulose as a scaffold, a highly porous, layered OA-BC catalyst was synthesized through an enhanced sol-gel process. This catalyst demonstrated exceptional performance in the oxidation of toluene, outperforming conventional alternatives that utilize chemical porogens. The OA-BC catalyst efficiently degrades toluene at 220degree celsius with high stability and hydrophobicity, indicating resistance to deactivation. Its superior activity is due to increased oxygen vacancies, enhanced metal oxide cooperation, and a layered porous structure, which together enhance active oxygen species and oxygen diffusion. Calcination of the OA-BC catalyst results in molecular cleavage and formation of small aggregates, increasing hydroxyl groups that stabilize Cu and Ce centers, enhancing toluene-oxygen reactions. In-situ infrared and X-ray photoelectron spectroscopy confirm stable monodentate Cu+ ligands, contributing to its high catalytic activity. This study introduces a novel approach by employing bacterial cellulose as a template for synthesizing a porous stratified OA-BC catalyst, demonstrating superior performance in toluene oxidation. The efficacy of catalyst results from a tripartite synergy involving the stratified porous architecture, the stabilizing effect of Cu+-coordinating ligands and hydroxyl groups, and the interplay of hydroxyl electron donors and acceptors, shedding light on environmentally benign catalyst development. |
| 分类号 | 一类 |
| WOS关键词 | BACTERIAL-CELLULOSE ; COMPOSITE OXIDE ; OXYGEN ; CO ; PERFORMANCE ; REDUCTION ; BEHAVIOR |
| 资助项目 | Guangxi Key Research and Development Program[2021AB25028] ; National Natural Science Foundation of China[22378008] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001209803500001 |
| 资助机构 | Guangxi Key Research and Development Program ; National Natural Science Foundation of China |
| 其他责任者 | Bin, Feng |
| 源URL | [http://dspace.imech.ac.cn/handle/311007/95037]  |
| 专题 | 力学研究所_高温气体动力学国家重点实验室 |
| 作者单位 | 1.Univ Sains Malaysia, Ctr Poliy Res & Int Studies, George Town 11800, Malaysia 2.Tianjin Univ Sci & Technol, Coll Marine & Environm Sci, Tianjin 30022, Peoples R China; 3.Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China; 4.Chinese Acad Sci, Inst Mech, State Key Lab High Temp Gas Dynam, Beijing 100190, Peoples R China; |
| 推荐引用方式 GB/T 7714 | Zhang CH,Liang, Wenjun,Dou, Baojuan,et al. Application insights of environmental catalysts: Synergistic effects of cellulose-based porogens and catalytic metal sites in toluene catalytic oxidation[J]. FUEL,2024,367:13. |
| APA | 张晨航.,Liang, Wenjun.,Dou, Baojuan.,Zhu, Yuxue.,Yan, Ningna.,...&宾峰.(2024).Application insights of environmental catalysts: Synergistic effects of cellulose-based porogens and catalytic metal sites in toluene catalytic oxidation.FUEL,367,13. |
| MLA | 张晨航,et al."Application insights of environmental catalysts: Synergistic effects of cellulose-based porogens and catalytic metal sites in toluene catalytic oxidation".FUEL 367(2024):13. |
入库方式： OAI收割
来源：力学研究所
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