Distinct structure-activity relationship and reaction mechanism over BaCoO3/CeO2 catalysts for NO direct decomposition
文献类型：期刊论文
| 作者 | Kang RN(康润宁) ; Wang, Xuehai; Huang JQ(黄俊钦); An, Sufeng; Wang, Lu; Wang, Gang; Chen, Hong; Zhang, Cuijuan; Bin F(宾峰); Li, Yongdan
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| 刊名 | APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
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| 出版日期 | 2024-08-05 |
| 卷号 | 350页码:13 |
| 关键词 | NO direct decomposition Perovskite BaCoO3 CeO2 morphology Reaction mechanism |
| ISSN号 | 0926-3373 |
| DOI | 10.1016/j.apcatb.2024.123952 |
| 通讯作者 | Wang, Gang(wanggang.fshy@sinopec.com) ; Bin, Feng(binfeng@imech.ac.cn) ; Li, Yongdan(yongdan.li@aalto.fi) |
| 英文摘要 | The dependency on morphology is crucial for achieving highly efficient direct decomposition of NO. Herein, a BaCoO3 /CeO2 catalyst is synthesized using CeO2 small particles (p), spheres (s) and rods (r) as supports. The NO conversion to N-2 (NTN2) at 800 C-degrees follows the order BaCoO3 /CeO2-r (78.8 %) > BaCoO3 /CeO2 -s (75.9 %) > BaCoO3 /CeO2 -p (56.9 %) > BaCoO3 (8.6 %) at a space velocity 1 g s/cm(3) . BaCoO3 /CeO2 -r exhibts high tolerance to O-2 and stability with conversion decreasing from 78.8 % to 74.6 %, 60.0 % and 50.0 % at 800 degrees C with 1, 5 and 10 vol% O-2 , respectively. The high redox activity, higher active oxygen mobility and NO adsorption capability ensures its superior performance, while the high surface area (31.29 m( 2)/g) and uniform distribution of active sites on the surface further promote the activity. The mechanism of NO direct decomposition is elucidated by in situ Diffuse reflectance infrared Fourier transform spectroscopy, O-18(2) isotopic transient exchange experiments and density functional theory (DFT) calculation. |
| 分类号 | 一类 |
| WOS关键词 | LOW-TEMPERATURE ; NITRIC-OXIDE ; FE ; CO ; PERFORMANCE ; REDUCTION ; OXIDATION ; N-2 ; COADSORPTION ; ADSORPTION |
| 资助项目 | International Science and Technology Cooperation Projects ; China Scholarship Council (CSC)[BX20230380] ; China National Postdoctoral Program for Innovative Talents[2023QN07] ; Youth Fund of the State Key Laboratory of High Temperature Gas Dynamics[202208320030] ; CSC[201906150134] ; CSC[202006120046] ; [202004910623] |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001222107500001 |
| 资助机构 | International Science and Technology Cooperation Projects ; China Scholarship Council (CSC) ; China National Postdoctoral Program for Innovative Talents ; Youth Fund of the State Key Laboratory of High Temperature Gas Dynamics ; CSC |
| 其他责任者 | Wang, Gang ; Bin, Feng ; Li, Yongdan |
| 源URL | [http://dspace.imech.ac.cn/handle/311007/95354]  |
| 专题 | 力学研究所_高温气体动力学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Kang RN,Wang, Xuehai,Huang JQ,et al. Distinct structure-activity relationship and reaction mechanism over BaCoO3/CeO2 catalysts for NO direct decomposition[J]. APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY,2024,350:13. |
| APA | 康润宁.,Wang, Xuehai.,黄俊钦.,An, Sufeng.,Wang, Lu.,...&Li, Yongdan.(2024).Distinct structure-activity relationship and reaction mechanism over BaCoO3/CeO2 catalysts for NO direct decomposition.APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY,350,13. |
| MLA | 康润宁,et al."Distinct structure-activity relationship and reaction mechanism over BaCoO3/CeO2 catalysts for NO direct decomposition".APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY 350(2024):13. |
入库方式： OAI收割
来源：力学研究所
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