Enantioselective Total Synthesis of the Cephalotaxus Alkaloid (-)-Cephalotine A
文献类型：期刊论文
| 作者 | Sheng,Peng-Zhen; Li,Lu-Lu; Ni,Zhi-Bin; Wei,Kun; Yang,Yu-Rong |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2023 |
| 关键词 | FORMAL TOTAL-SYNTHESIS ALPHA-ALLYLATION UNIFIED STRATEGY NATURAL-PRODUCTS GAMMA-LACTAMS HECK REACTION (+/-)-CEPHALOTAXINE REARRANGEMENT C |
| ISSN号 | 1523-7052 |
| DOI | 10.1021/acs.orglett.3c02097 |
| 英文摘要 | Cephalotine A, a recently isolated Cephalotaxus alkaloid,was firstsynthesized enantioselectively through three critical reactions. SmI2 -mediated radical cyclization of lactone and aldehyde toforge the final ring system, Chang's iridium-catalyzed C-Hamidation to construct pyrrolidone stereoselectively, and Carreria'sdual Ir/amine catalyzed allylation to install the vicinal tertiarystereocenters. |
| WOS记录号 | WOS:001047853100001 |
| 源URL | [http://ir.kib.ac.cn/handle/151853/75283]  |
| 专题 | 中国科学院昆明植物研究所 |
| 推荐引用方式 GB/T 7714 | Sheng,Peng-Zhen,Li,Lu-Lu,Ni,Zhi-Bin,et al. Enantioselective Total Synthesis of the Cephalotaxus Alkaloid (-)-Cephalotine A[J]. ORGANIC LETTERS,2023. |
| APA | Sheng,Peng-Zhen,Li,Lu-Lu,Ni,Zhi-Bin,Wei,Kun,&Yang,Yu-Rong.(2023).Enantioselective Total Synthesis of the Cephalotaxus Alkaloid (-)-Cephalotine A.ORGANIC LETTERS. |
| MLA | Sheng,Peng-Zhen,et al."Enantioselective Total Synthesis of the Cephalotaxus Alkaloid (-)-Cephalotine A".ORGANIC LETTERS (2023). |
入库方式： OAI收割
来源：昆明植物研究所
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