Total Synthesis of Starfish Cyclic Steroid Glycosides. Part 2, Model Synthesis via Intramolecular Etherification
文献类型：期刊论文
| 作者 | Chen,Youxi; Xiao,Guozhi; Zhu,Dapeng; Yu,Biao |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2023 |
| 卷号 | 41期号:8页码:897-902 |
| 关键词 | Cyclic starfish glycosides Au(I) catalysis Epoxide Glycosylation Cyclization ALKYNYLBENZOATES |
| ISSN号 | 1614-7065 |
| DOI | 10.1002/cjoc.202200786 |
| 英文摘要 | Sepositoside A (1) is a prototypical cyclic steroid glycoside bearing a hybrid 16-membered ring composed of the steroid skeleton and a 1,2-trans-linked trisaccharide. Herein, we report an expedient access toward two simplified analogues, in which the strained 16-membered ring is constructed via Au(I)-catalyzed intramolecular addition of alcohol to epoxide. A similar macroetherification in relevant steroid trisaccharides has been intensively examined, however, failed to furnish the macrocyclic skeleton of Sepositoside A. |
| 学科主题 | Chemistry |
| WOS记录号 | WOS:000938072000001 |
| 源URL | [http://ir.kib.ac.cn/handle/151853/75321]  |
| 专题 | 中国科学院昆明植物研究所 |
| 推荐引用方式 GB/T 7714 | Chen,Youxi,Xiao,Guozhi,Zhu,Dapeng,et al. Total Synthesis of Starfish Cyclic Steroid Glycosides. Part 2, Model Synthesis via Intramolecular Etherification[J]. CHINESE JOURNAL OF CHEMISTRY,2023,41(8):897-902. |
| APA | Chen,Youxi,Xiao,Guozhi,Zhu,Dapeng,&Yu,Biao.(2023).Total Synthesis of Starfish Cyclic Steroid Glycosides. Part 2, Model Synthesis via Intramolecular Etherification.CHINESE JOURNAL OF CHEMISTRY,41(8),897-902. |
| MLA | Chen,Youxi,et al."Total Synthesis of Starfish Cyclic Steroid Glycosides. Part 2, Model Synthesis via Intramolecular Etherification".CHINESE JOURNAL OF CHEMISTRY 41.8(2023):897-902. |
入库方式： OAI收割
来源：昆明植物研究所
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