Shape-persistent phthalocyanine cages
文献类型：期刊论文
| 作者 | Hu,Yiming; Huang,Shaoda; Wayment,Lacey J.; Wu,Jingyi; Xu,Qiucheng; Chang,Tieyan; Chen,Ying-Pin; Li,Xiaonian; Andi,Babak; Chen,Hongxuan |
| 刊名 | CELL REPORTS PHYSICAL SCIENCE
 |
| 出版日期 | 2023 |
| 卷号 | 4期号:2页码:101285 |
| 关键词 | PALLADIUM NANOPARTICLES MOLECULAR CAGE ORGANIC CAGE PERFORMANCE CATALYSTS |
| ISSN号 | 2666-3864 |
| DOI | 10.1016/j.xcrp.2023.101285 |
| 英文摘要 | Phthalocyanine (Pc), an electro-redox active moiety, has many attractive properties stemming from its large aromatic system and ability to act as a catalyst in electrochemical reactions, such as the CO2 reduction reaction (CO2RR). However, due to the synthetic chal-lenge related to geometric requirements and poor solubility (strong aggregation), discrete shape-persistent cages consisting of site -iso-lated, readily accessible Pc moieties have not been available. Here, we report the synthesis of Zn-and Ni-metallated Pc-based molecular cages via one-step dynamic spiroborate linkage formation in high yields. The ZnPc cage structure is unambiguously elucidated at the atomic level by single-crystal X-ray diffraction. Moreover, owing to the site-isolated redox-active metal centers, readily accessible intrinsic cavity, and shape-persistent backbone, the Ni-metallated Pc (NiPc) cage exhibits high catalytic efficiency, selectivity, and sta-bility, superior to the non-caged control molecules in electrocata-lytic CO2RR. |
| 学科主题 | Chemistry ; Energy & Fuels ; Materials Science ; Physics |
| WOS记录号 | WOS:000961505700001 |
| 源URL | [http://ir.kib.ac.cn/handle/151853/75447]  |
| 专题 | 中国科学院昆明植物研究所 |
| 推荐引用方式 GB/T 7714 | Hu,Yiming,Huang,Shaoda,Wayment,Lacey J.,et al. Shape-persistent phthalocyanine cages[J]. CELL REPORTS PHYSICAL SCIENCE,2023,4(2):101285. |
| APA | Hu,Yiming.,Huang,Shaoda.,Wayment,Lacey J..,Wu,Jingyi.,Xu,Qiucheng.,...&Zhang,Wei.(2023).Shape-persistent phthalocyanine cages.CELL REPORTS PHYSICAL SCIENCE,4(2),101285. |
| MLA | Hu,Yiming,et al."Shape-persistent phthalocyanine cages".CELL REPORTS PHYSICAL SCIENCE 4.2(2023):101285. |
入库方式： OAI收割
来源：昆明植物研究所
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