Spatially Selective Solvation Structure by Electronegative Micro-Arrays for Stable Lithium-Metal Anode Interface
文献类型：期刊论文
| 作者 | Shen, Haorui2; Yu, Tong2; Tang, Pei2,4; Yang, Huicong2; Tan, Jun1,3; Bai, Shuo2,4; Li, Feng2,4 |
| 刊名 | ADVANCED MATERIALS
 |
| 出版日期 | 2023-12-13 |
| 页码 | 9 |
| 关键词 | anion-cation interaction lithium metal batteries micro-arrays solid electrolyte interfaces solvation structures |
| ISSN号 | 0935-9648 |
| DOI | 10.1002/adma.202306553 |
| 通讯作者 | Tan, Jun(tanjun@jihualab.ac.cn) ; Bai, Shuo(sbai@imr.ac.cn) ; Li, Feng(fli@imr.ac.cn) |
| 英文摘要 | For electrolytes with conventional lithium salt concentration, it is not easy to generate sufficient anion-derived beneficial inorganic components to stabilize the electrolyte-lithium metal anode interface due to the repulsion of the free-state anions by the anode. In this study, the above issues are solved through the strong interaction between electronegative materials and lithium ions (Li+). A locally high Li+ concentration strategy is proposed by preparing micro-arrays of electronegative nano-hydroxyapatite (nHA) on the Cu foil. It is found that the oxygen atoms in the phosphate group (-PO4) of the nHA can strongly adsorb Li+ to form a locally Li+-rich region, which increases the probability of anions interacting with Li+. The formation of more Li+-coordinated anions at the electrolyte-anode interface can reduce the Li+ de-solvation energy barrier, and enable the anions to completely decompose into lithium fluoride (LiF) and lithium nitride (Li3N) on the Li metal anode. The interfacial transfer dynamics is accelerated and the Li dendrites are effectively suppressed. Under high current density, the anode exhibits a long lifespan with high Coulombic efficiency and small polarization voltage. The nHA micro-arrays achieve the targeted solvation structure at the electrolyte-anode interface while ensuring conventional lithium salt concentration in the bulk electrolyte. Nano-hydroxyapatite (nHA) exhibits a high Li+ binding energy of -5.99 eV. With nHA micro-arrays on the Cu foil, a locally Li+-rich region forms at the electrolyte-anode interface, which can promote the generation of aggregates (AGGs) of anions. The decomposition efficiency of anions is significantly improved, leading to the formation of a more protective solid electrolyte interface (SEI) film.image |
| 资助项目 | National Natural Science Foundation of China ; National Key R&D Program of China[2021YFB3800300] ; National Key R&D Program of China[2022YFB3803400] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA22010602] ; Key R&D Plan of Jihua Laboratory[X200191TL200] ; China National Postdoctoral Program for Innovative Talents[BX2021321] ; China Postdoctoral Science Foundation[2022M713214] ; China Postdoctoral Science Foundation[2022M723216] ; [51927803] ; [52020105010] ; [22209189] ; [52203364] ; [52188101] ; [22309192] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:001123291000001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China ; National Key R&D Program of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Key R&D Plan of Jihua Laboratory ; China National Postdoctoral Program for Innovative Talents ; China Postdoctoral Science Foundation |
| 源URL | [http://ir.imr.ac.cn/handle/321006/177150]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Tan, Jun; Bai, Shuo; Li, Feng |
| 作者单位 | 1.Foshan Univ, Sch Mechatron Engn & Automat, Foshan 528000, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Test & Anal Ctr, Jihua Lab, Foshan 528200, Peoples R China 4.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shen, Haorui,Yu, Tong,Tang, Pei,et al. Spatially Selective Solvation Structure by Electronegative Micro-Arrays for Stable Lithium-Metal Anode Interface[J]. ADVANCED MATERIALS,2023:9. |
| APA | Shen, Haorui.,Yu, Tong.,Tang, Pei.,Yang, Huicong.,Tan, Jun.,...&Li, Feng.(2023).Spatially Selective Solvation Structure by Electronegative Micro-Arrays for Stable Lithium-Metal Anode Interface.ADVANCED MATERIALS,9. |
| MLA | Shen, Haorui,et al."Spatially Selective Solvation Structure by Electronegative Micro-Arrays for Stable Lithium-Metal Anode Interface".ADVANCED MATERIALS (2023):9. |
入库方式： OAI收割
来源：金属研究所
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