Recent advances in metal-based electrocatalysts: from fundamentals and structural regulations to applications in anion-exchange membrane fuel cells
文献类型：期刊论文
| 作者 | Han, Ali2; Liu, Gang1,2 |
| 刊名 | MATERIALS CHEMISTRY FRONTIERS
 |
| 出版日期 | 2023-12-04 |
| 页码 | 27 |
| DOI | 10.1039/d3qm00947e |
| 通讯作者 | Liu, Gang(gangliu@imr.ac.cn) |
| 英文摘要 | Alkaline exchange membrane fuel cells (AEMFCs) have broad application prospects due to the use of low-cost, non-precious catalysts. Furthermore, a wide range of fuels, for example, carbon-neutral hydrogen (H2) and ammonia (NH3), can be directly used in H2-fueled AEMFCs and NH3-fueled AEM direct ammonia fuel cells (AEM-DAFCs). However, the development of the above-mentioned AEMFCs is hindered by the sluggish dynamics of the alkaline hydrogen oxidation reaction (HOR), ammonium oxidation reaction (AOR), and oxygen reduction reaction (ORR) and low efficiency catalysts for these electrode reactions. Thus, it is expected that the rational design and controlled synthesis of highly efficient, durable catalysts will enable AEMFCs to achieve comparable performance to or even a higher performance than that of proton exchange membrane fuel cells (PEMFCs), which usually require high-cost platinum group metals (PGMs). In particular, the proposed catalytic mechanism of these reactions in alkaline media is still under debate, especially of the HOR and AOR. Herein, we present an in-depth, comprehensive understanding of the alkaline HOR, AOR, and ORR based on metal catalysts, especially employing PGM-free catalysts, including the proposed mechanisms and the current development of catalysts and AEMFCs. Finally, we highlight the prevailing challenge of the mechanisms and catalysts for each reaction and outline the possible development directions for AEMFCs. We anticipate that this review will offer global scientific insights and a roadmap for the design of catalysts for alkaline electrode reactions to accelerate the further development of AEMFC technology. We present a comprehensive understanding of the alkaline hydrogen oxidation reaction (HOR), ammonium oxidation reaction (AOR), and oxygen reduction reaction (ORR) based on metal catalysts for H2 or NH3-fueled alkaline exchange membrane fuel cells. |
| 资助项目 | National Natural Science Foundation of China[22202214] ; National Natural Science Foundation of China[51825204] ; National Natural Science Foundation of China[2022-YQ-02] ; Natural Science Foundation of Liaoning Province-Outstanding Youth Foundation ; New Cornerstone Science Foundation through the XPLORER PRIZE |
| WOS研究方向 | Chemistry ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:001112657000001 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; Natural Science Foundation of Liaoning Province-Outstanding Youth Foundation ; New Cornerstone Science Foundation through the XPLORER PRIZE |
| 源URL | [http://ir.imr.ac.cn/handle/321006/177282]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Liu, Gang |
| 作者单位 | 1.Univ Sci & Technol China, Sch Mat Sci & Engn, 72 Wenhua Rd, Shenyang 110016, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Han, Ali,Liu, Gang. Recent advances in metal-based electrocatalysts: from fundamentals and structural regulations to applications in anion-exchange membrane fuel cells[J]. MATERIALS CHEMISTRY FRONTIERS,2023:27. |
| APA | Han, Ali,&Liu, Gang.(2023).Recent advances in metal-based electrocatalysts: from fundamentals and structural regulations to applications in anion-exchange membrane fuel cells.MATERIALS CHEMISTRY FRONTIERS,27. |
| MLA | Han, Ali,et al."Recent advances in metal-based electrocatalysts: from fundamentals and structural regulations to applications in anion-exchange membrane fuel cells".MATERIALS CHEMISTRY FRONTIERS (2023):27. |
入库方式： OAI收割
来源：金属研究所
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