Evidence for an Interface of Hybrid Cocatalysts Favoring Photocatalytic Hydrogen Evolution Kinetics
文献类型：期刊论文
| 作者 | Xie, Yingpeng3; Chang, Junhua3; Zheng, Peng3; Zhang, Lili1; Xie, Tengfeng2; Jiang, Renzheng3; Zhang, Zhanguo3; Yang, Yongqiang1; Zou, Mengke1; Yin, Lichang1 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2023-10-30 |
| 页码 | 10 |
| 关键词 | photocatalytic hybrid cocatalysts interfaces hydrogen evolution kinetics |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/acsami.3c10097 |
| 通讯作者 | Xie, Yingpeng(ypxie@syuct.edu.cn) ; Xu, Guangwen(gwxu@syuct.edu.cn) |
| 英文摘要 | Hybrid cocatalysts have great application potential for improving the photocatalytic hydrogen evolution performance of semiconductors. The interfaces between components of hybrid cocatalysts make a great contribution to the improvement, but the associated mechanisms remain unclear. Herein, we prepared and tested three comparative CdS-based photocatalysts with NiS, NiS/Ni9S8, and Ni9S8 as the cocatalysts separately. The emphasis is placed on investigating the effect of the NiS/Ni9S8 interfaces on the photocatalytic hydrogen evolution performance of CdS. NiS/Ni9S8 exhibits a higher ability than NiS and Ni9S8 in making CdS a more active photocatalyst for water splitting. It shows that NiS, NiS/Ni9S8, and Ni9S8 perform similarly in terms of promoting the charge transfer and separation of CdS based on steady-state and time-resolved photoluminescence studies. At the same time, the linear sweep voltammetry and electrochemical impedance spectroscopy tests combined with the density functional theory calculations reveal that the component interfaces of NiS/Ni9S8 enable us to lower the water splitting activation energy, the charge-transfer resistance from the cocatalyst to sacrificial agent, and hydrogen adsorption Gibbs free energy. It is evidenced from this work that component interfaces of hybrid cocatalysts play a vital role in accelerating the dynamics of hydrogen evolution reactions. |
| 资助项目 | National Key R&D Program of China[2022YFF0705104] ; National Natural Science Foundation of China[51402199] ; National Natural Science Foundation of China[U21A20316] ; Liaoning Revitalization Talents Program[XLYC2007193] ; Natural Science Foundation of Liaoning Province[2021NLTS1210] |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:001096851100001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Liaoning Revitalization Talents Program ; Natural Science Foundation of Liaoning Province |
| 源URL | [http://ir.imr.ac.cn/handle/321006/177653]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Xie, Yingpeng; Xu, Guangwen |
| 作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Jilin Univ, Coll Chem, State Key Lab Theoret & Computat Chem, Changchun 130012, Peoples R China 3.Shenyang Univ Chem Technol, Key Lab Resources Chem & Mat, Minist Educ, Shenyang 110142, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xie, Yingpeng,Chang, Junhua,Zheng, Peng,et al. Evidence for an Interface of Hybrid Cocatalysts Favoring Photocatalytic Hydrogen Evolution Kinetics[J]. ACS APPLIED MATERIALS & INTERFACES,2023:10. |
| APA | Xie, Yingpeng.,Chang, Junhua.,Zheng, Peng.,Zhang, Lili.,Xie, Tengfeng.,...&Xu, Guangwen.(2023).Evidence for an Interface of Hybrid Cocatalysts Favoring Photocatalytic Hydrogen Evolution Kinetics.ACS APPLIED MATERIALS & INTERFACES,10. |
| MLA | Xie, Yingpeng,et al."Evidence for an Interface of Hybrid Cocatalysts Favoring Photocatalytic Hydrogen Evolution Kinetics".ACS APPLIED MATERIALS & INTERFACES (2023):10. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。