Green and efficient synthesis of hierarchical porous carbon derived from MOF-235 for catalytic degradation of thiocyanate
文献类型：期刊论文
| 作者 | Yang, Yang2,3; Li, Binchuan2,3; Fu, Daxue2,3; Chen, Jianshe2,3; Cui, Shuang4; He, Xiaocai5; Liu, Kuiren2,3; Wei, Shicheng1; Li, Da6; Han, Qing2,3 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2023-10-16 |
| 卷号 | 25期号:20页码:8093-8107 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/d3gc02608f |
| 通讯作者 | Han, Qing(hanq@smm.neu.edu.cn) |
| 英文摘要 | Metal-organic framework-derived carbon-based materials have shown significant potential in advanced oxidation processes. However, mass production of MOFs is still limited mainly due to non-economic, non-green, and complex synthesis methods. This study reports thermal-assisted ball milling as a novel method for the green and efficient synthesis of MOF-235 compared with the solvothermal method. Lamellar metal-free porous carbon was obtained by pyrolysis of MOF-235 and HCl etching to avoid secondary pollution from metal leaching in activating persulfate for thiocyanate degradation. The effect of pyrolysis temperature on the structural characteristics and catalytic performance of MOF-235-derived porous carbon was investigated. The results demonstrated that the porous carbon derived from pyrolysis of MOF-235 at 650 degrees C with a larger specific surface area (831.48 m2 g-1) and a higher sp2-hybridized structure (70.3%) exhibits superior catalytic activity in persulfate activation, as evidenced by 99.9% degradation of thiocyanate within 15 min with 0.4 g L-1 catalyst and [Na2S2O8] : [SCN-] = 6.0 at ambient pH (5.5). The thiocyanate degradation experiments and mechanism studies revealed that the dominant pathways were the singlet oxygen-mediated non-radical oxidation and electron transfer processes. Finally, a possible mechanism of persulfate activation on metal-free porous carbon was proposed. This work provides thermal-assisted ball milling as a feasible method for the synthesis of MOF-235 and also discusses the promising application of the derived carbon for persulfate activation in wastewater treatment. Thermal-assisted ball milling is a novel method for the green and efficient synthesis of MOF-235. MOF-235-derived porous carbon exhibits excellent catalytic performance in thiocyanate degradation by persulfate activation. |
| 资助项目 | This work was supported by the Fundamental Research Funds for the Central Universities under Grants (N2225019), the Fundamental Research Funds for the Central Universities (N2125031), and the National Natural Science Foundation of China (41773093). |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics |
| 语种 | 英语 |
| WOS记录号 | WOS:001062495200001 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | This work was supported by the Fundamental Research Funds for the Central Universities under Grants (N2225019), the Fundamental Research Funds for the Central Universities (N2125031), and the National Natural Science Foundation of China (41773093). |
| 源URL | [http://ir.imr.ac.cn/handle/321006/177674]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Han, Qing |
| 作者单位 | 1.Army Acad Armored Forces, Natl Key Lab Remfg, Beijing 100072, Peoples R China 2.Minist Educ, Key Lab Ecol Utilizat Multimetall Mineral, Shenyang 110819, Peoples R China 3.Northeastern Univ, Sch Met, Shenyang 110819, Peoples R China 4.Shenyang Ligong Univ, Coll Environm & Chem Engn, Shenyang, Peoples R China 5.Kunming Met Res Inst, Kunming 650500, Yunnan, Peoples R China 6.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Yang,Li, Binchuan,Fu, Daxue,et al. Green and efficient synthesis of hierarchical porous carbon derived from MOF-235 for catalytic degradation of thiocyanate[J]. GREEN CHEMISTRY,2023,25(20):8093-8107. |
| APA | Yang, Yang.,Li, Binchuan.,Fu, Daxue.,Chen, Jianshe.,Cui, Shuang.,...&Han, Qing.(2023).Green and efficient synthesis of hierarchical porous carbon derived from MOF-235 for catalytic degradation of thiocyanate.GREEN CHEMISTRY,25(20),8093-8107. |
| MLA | Yang, Yang,et al."Green and efficient synthesis of hierarchical porous carbon derived from MOF-235 for catalytic degradation of thiocyanate".GREEN CHEMISTRY 25.20(2023):8093-8107. |
入库方式： OAI收割
来源：金属研究所
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