Dispersive adsorption and anticorrosion properties of natural capsaicin on Q235 steel in mixed H2SO4 and NaCl environment: Characterization, experimental and theoretical studies
文献类型：期刊论文
| 作者 | Emori, Wilfred1,5; Louis, Hitler6; Okonkwo, Paul C.2; Njoku, Demian I.3,4; Edet, Henry O.6; Okafor, Peter C.9; Cheng, Chun-Ru1,4,7,8 |
| 刊名 | SUSTAINABLE CHEMISTRY AND PHARMACY
 |
| 出版日期 | 2023-05-01 |
| 卷号 | 32页码:18 |
| 关键词 | Phytochemical Adsorption Capsaicin Q235 steel Electrochemistry Computation |
| DOI | 10.1016/j.scp.2023.101042 |
| 通讯作者 | Emori, Wilfred(wemori@suse.edu.cn) ; Njoku, Demian I.(demianifeanyi@gmail.com) ; Cheng, Chun-Ru(pharmaceutics@163.com) |
| 英文摘要 | Although traditional corrosion inhibitors have demonstrated immense relevance in metal protec-tion for many years now, issues relating to their moderate to high toxicities, non-biodegradability, and cost-effectiveness have persisted. For these reasons, bio-based corrosion in-hibitors are gathering significant research attention and have shown great potentials in the corro-sion suppression of metals while being relatively cheap and eco-friendly. This study focuses on the anticorrosion and adsorption properties of natural capsaicin isolated from Capsicum annuum L. as a bio-based corrosion inhibitor for Q235 steel in a mixed acid and chloride system (0.25 M H2SO4 + 0.5 M NaCl). FTIR and NMR techniques afforded the characterization and identifica-tion of the phytocompound. Electrochemical and gravimetric measurements were employed for anticorrosion evaluations. 3D surface profilometer, SEM, and water contact angle examinations provided adsorption proof for capsaicin on steel surface. XPS provided insights into the corrosion suppression mechanism of capsaicin. Computational techniques allowed the description of the adsorption characteristics, molecular interactions, molecular orientations and binding energies of capsaicin on steel substrate. Having a maximum inhibition performance of 94.8% at 298 K, cap-saicin was classified as a functional mixed-type corrosion inhibitor that is reliant on concentra-tion and surrounding temperature for its effectiveness. While also validating the results from wa-ter contact angle measurements, 3D profiling, and SEM, XPS results disclosed that the interac-tions of capsaicin with steel surface leading to its adsorption and anticorrosion effect involved both physisorption and chemisorption processes, and this was in perfect correlation with the Langmuir monolayer adsorption model. |
| 资助项目 | Key Laboratories of Fine Chemicals and Surfactants in Sichuan Provincial Universities[2019JXZ02] ; Key Laboratory of Green Chemistry of Sichuan Institutes of Higher Education[LZJ18202] ; Central Guidance on Local Science and Technology Development Fund of Sichuan Province[2021ZYD0062] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:001001245400001 |
| 出版者 | ELSEVIER |
| 资助机构 | Key Laboratories of Fine Chemicals and Surfactants in Sichuan Provincial Universities ; Key Laboratory of Green Chemistry of Sichuan Institutes of Higher Education ; Central Guidance on Local Science and Technology Development Fund of Sichuan Province |
| 源URL | [http://ir.imr.ac.cn/handle/321006/178132]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Emori, Wilfred; Njoku, Demian I.; Cheng, Chun-Ru |
| 作者单位 | 1.Key Lab Mat Corros & Protect Sichuan Prov, Zigong 643000, Sichuan, Peoples R China 2.Dhofar Univ, Mech & Mechatron Engn, Salalah, Oman 3.Chinese Acad Sci, Inst Met Res, Ctr Corros & Protect Mat, Shenyang 110016, Peoples R China 4.Hong Kong Metropolitan Univ, Sch Sci & Technol, Dept Appl Sci, Good Shepherd St, Ho Man Tin, Peoples R China 5.Sichuan Univ Sci & Engn, Sch Mat Sci & Engn, Zigong 643000, Sichuan, Peoples R China 6.Univ Calabar, Computat & Biosimulat Res Grp, Calabar, Nigeria 7.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochemistry & Plant Resources Wes, Lanhei Rd 132, Kunming 650201, Yunnan, Peoples R China 8.Sichuan Univ Sci & Engn, Inst Pharmaceut Engn Technol & Applicat, Key Lab Green Chem Sichuan Inst Higher Educ, Coll Chem Engn, Zigong 643000, Sichuan, Peoples R China 9.Univ Calabar, Dept Pure & Appl Chem, Corros & Electrochem Res Grp, PMB 1115, Calabar, Nigeria |
| 推荐引用方式 GB/T 7714 | Emori, Wilfred,Louis, Hitler,Okonkwo, Paul C.,et al. Dispersive adsorption and anticorrosion properties of natural capsaicin on Q235 steel in mixed H2SO4 and NaCl environment: Characterization, experimental and theoretical studies[J]. SUSTAINABLE CHEMISTRY AND PHARMACY,2023,32:18. |
| APA | Emori, Wilfred.,Louis, Hitler.,Okonkwo, Paul C..,Njoku, Demian I..,Edet, Henry O..,...&Cheng, Chun-Ru.(2023).Dispersive adsorption and anticorrosion properties of natural capsaicin on Q235 steel in mixed H2SO4 and NaCl environment: Characterization, experimental and theoretical studies.SUSTAINABLE CHEMISTRY AND PHARMACY,32,18. |
| MLA | Emori, Wilfred,et al."Dispersive adsorption and anticorrosion properties of natural capsaicin on Q235 steel in mixed H2SO4 and NaCl environment: Characterization, experimental and theoretical studies".SUSTAINABLE CHEMISTRY AND PHARMACY 32(2023):18. |
入库方式： OAI收割
来源：金属研究所
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