Metal-Free Electrocatalysts for the Selective 2 e(-) Oxygen Reduction Reaction: A Never-Ending Story?
文献类型：期刊论文
| 作者 | Tuci, Giulia1,7; Rossin, Andrea1,7; Zhang, Xiong5,6; Truong-Phuoc, Lai6; Berretti, Enrico1,7; Liu, Yuefeng4; Pham-Huu, Cuong6; Ali, Sajjad3; Jan, Faheem2; Poggini, Lorenzo1,7 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2023-06-16 |
| 页码 | 11 |
| 关键词 | 2e(-) oxygen reduction reaction carbon nanomaterials functionalization electrocatalyst surface chemical engineering hydrogen peroxide production metal-free electrocatalysts |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.202301036 |
| 通讯作者 | Tuci, Giulia(giulia.tuci@iccom.cnr.it) ; Giambastiani, Giuliano(giuliano.giambastiani@iccom.cnr.it) |
| 英文摘要 | Hydrogen peroxide (H2O2) electrosynthesis via the 2e(-) Oxygen Reduction Reaction (ORR) represents a highly challenging, environmentally friendly and cost-effective alternative to the current anthraquinone-based technology. Various lightweight element hetero-doped carbon nanostructures are promising and cheap metal-free electrocatalysts for H2O2 synthesis, particularly those containing O-functionalities. The exact role of O-containing functional groups as electroactive sites for the process remains debated if not highly controversial. Herein, we have reported on the covalent exohedral functionalization of the outer surface of extra-pure multi-walled carbon nanotubes (MWCNTs) with discrete O-functional groups as a unique approach to prepare selective electrocatalysts for the process. This kind of decoration has added fundamental tiles to the puzzling structure/reactivity relationship of O-containing carbon-based catalysts for ORR, clearing doubts on the controversial role of hydroxyl/phenol groups as key functionalities for the design of more performing 2e(-) ORR electrocatalysts. |
| 资助项目 | TRAINER project (Catalysts for Transition to Renewable Energy Future) of the Make our Planet Great Again program[ANR-17-MPGA-0017] ; Italian MIUR[20179337R7] ; CAS President's International Fellowship Initiative (PIFI) program |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:001009692700001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | TRAINER project (Catalysts for Transition to Renewable Energy Future) of the Make our Planet Great Again program ; Italian MIUR ; CAS President's International Fellowship Initiative (PIFI) program |
| 源URL | [http://ir.imr.ac.cn/handle/321006/178180]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Tuci, Giulia; Giambastiani, Giuliano |
| 作者单位 | 1.ICCOM CNR, Inst Chem OrganoMetall Cpds, Via Madonna Piano 10 Sesto F, I-50019 Florence, Italy 2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China 3.Univ Elect Sci & Technol China, Yangtze Delta Reg Inst Huzhou, Huzhou 313001, Peoples R China 4.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy DNL, 457 Zhongshan Rd, Dalian 116023, Peoples R China 5.Chinese Acad Sci, Dalian Inst Chem Phys, CAS Key Lab Sci & Technol Appl Catalysis, Dalian 116023, Peoples R China 6.Univ Strasbourg, Inst Chem & Proc Energy Environm & Hlth ICPEES, ECPM, CNRS,UMR 7515, 25 Rue Becquerel, F-67087 Strasbourg 02, France 7.Consorzio INSTM, Via Madonna Piano 10 Sesto F, I-50019 Florence, Italy |
| 推荐引用方式 GB/T 7714 | Tuci, Giulia,Rossin, Andrea,Zhang, Xiong,et al. Metal-Free Electrocatalysts for the Selective 2 e(-) Oxygen Reduction Reaction: A Never-Ending Story?[J]. CHEMISTRY-A EUROPEAN JOURNAL,2023:11. |
| APA | Tuci, Giulia.,Rossin, Andrea.,Zhang, Xiong.,Truong-Phuoc, Lai.,Berretti, Enrico.,...&Giambastiani, Giuliano.(2023).Metal-Free Electrocatalysts for the Selective 2 e(-) Oxygen Reduction Reaction: A Never-Ending Story?.CHEMISTRY-A EUROPEAN JOURNAL,11. |
| MLA | Tuci, Giulia,et al."Metal-Free Electrocatalysts for the Selective 2 e(-) Oxygen Reduction Reaction: A Never-Ending Story?".CHEMISTRY-A EUROPEAN JOURNAL (2023):11. |
入库方式： OAI收割
来源：金属研究所
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