Platinum-Lead-Bismuth/Platinum-Bismuth Core/Shell Nanoplate Achieves Complete Dehydrogenation Pathway for Direct Formic Acid Oxidation Catalysis
文献类型：期刊论文
| 作者 | Hu, Xinrui6; Xiao, Zhengyi6; Wang, Weizhen4; Bu, Lingzheng3; An, Zhengchao6; Liu, Shangheng6; Pao, Chih-Wen5; Zhan, Changhong6; Hu, Zhiwei1; Yang, Zhiqing2 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2023-06-08 |
| 页码 | 9 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/jacs.3c00262 |
| 通讯作者 | Bu, Lingzheng(lzbu@xmu.edu.cn) ; Huang, Xiaoqing(hxq006@xmu.edu.cn) |
| 英文摘要 | Designingplatinum (Pt)-based formic acid oxidation reaction (FAOR)catalysts with high performance and high selectivity of direct dehydrogenationpathway for direct formic acid fuel cell (DFAFC) is desirable yetchallenging. Herein, we report a new class of surface-uneven PtPbBi/PtBicore/shell nanoplates (PtPbBi/PtBi NPs) as the highly active and selectiveFAOR catalysts, even in the complicated membrane electrode assembly(MEA) medium. They can achieve unprecedented specific and mass activitiesof 25.1 mA cm(-2) and 7.4 A mg(Pt) (-1) for FAOR, 156 and 62 times higher than those of commercial Pt/C,respectively, which is the highest for a FAOR catalyst by far. Simultaneously,they show highly weak adsorption of CO and high dehydrogenation pathwayselectivity in the FAOR test. More importantly, the PtPbBi/PtBi NPscan reach the power density of 161.5 mW cm(-2), alongwith a stable discharge performance (45.8% decay of power densityat 0.4 V for 10 h), demonstrating great potential in a single DFAFCdevice. The in situ Fourier transform infrared spectroscopy(FTIR) and X-ray absorption spectroscopy (XAS) results collectivelyreveal a local electron interaction between PtPbBi and PtBi. In addition,the high-tolerance PtBi shell can effectively inhibit the production/adsorptionof CO, resulting in the complete presence of the dehydrogenation pathwayfor FAOR. This work demonstrates an efficient Pt-based FAOR catalystwith 100% direct reaction selectivity, which is of great significancefor driving the commercialization of DFAFC. |
| 资助项目 | National Key R&D Program of China[2020YFB1505802] ; Ministry of Science and Technology of China[2017YFA0208200] ; National Natural Science Foundation of China[22025108] ; National Natural Science Foundation of China[U21A20327] ; National Natural Science Foundation of China[22121001] ; Xiamen University |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:001004388000001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Key R&D Program of China ; Ministry of Science and Technology of China ; National Natural Science Foundation of China ; Xiamen University |
| 源URL | [http://ir.imr.ac.cn/handle/321006/178291]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 通讯作者 | Bu, Lingzheng; Huang, Xiaoqing |
| 作者单位 | 1.Max Planck Inst Chem Phys Solids, Coll Chem, D-01187 Dresden, Germany 2.Ji Hua Lab, Foshan 528200, Peoples R China 3.Xiamen Univ, Coll Energy, Xiamen 361102, Peoples R China 4.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 5.Natl Synchrotron Radiat Res Ctr, Hsinchu 30076, Taiwan 6.Xiamen Univ, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Xinrui,Xiao, Zhengyi,Wang, Weizhen,et al. Platinum-Lead-Bismuth/Platinum-Bismuth Core/Shell Nanoplate Achieves Complete Dehydrogenation Pathway for Direct Formic Acid Oxidation Catalysis[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2023:9. |
| APA | Hu, Xinrui.,Xiao, Zhengyi.,Wang, Weizhen.,Bu, Lingzheng.,An, Zhengchao.,...&Huang, Xiaoqing.(2023).Platinum-Lead-Bismuth/Platinum-Bismuth Core/Shell Nanoplate Achieves Complete Dehydrogenation Pathway for Direct Formic Acid Oxidation Catalysis.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,9. |
| MLA | Hu, Xinrui,et al."Platinum-Lead-Bismuth/Platinum-Bismuth Core/Shell Nanoplate Achieves Complete Dehydrogenation Pathway for Direct Formic Acid Oxidation Catalysis".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023):9. |
入库方式： OAI收割
来源：金属研究所
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